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Vol 51, No 11-12 (2016)

Research, Design, Calculations, and Operating Experience

An Entropy-Statistical Analysis of a Natural Gas Liquefaction Plant with External Nitrogen Cooling Cycle

Arkharov A.M., Semenov V.Y., Krasnonosova S.D.

Abstract

An entropy-statistical analysis of a 7 tons/h capacity small-tonnage CNG plant functioning in a cycle with external nitrogen expansion cooling demonstrated a probable value of the magnitude of thermodynamic perfection of 33%. Application of a rational multi-stage scheme with pre-cooling and the use of a compressor with isothermal efficiency 0.65 and turbine expansion engine with adiabatic efficiency 0.835 are responsible for the decisive contribution to achieving an increase in efficiency.

Chemical and Petroleum Engineering. 2016;51(11-12):725-735
pages 725-735 views

Study of Convective Heat Transfer of Combustion Products of Fuels

Vetkin A.V., Suris A.L.

Abstract

Convective heat transfer after combustion of gaseous fuels, which are used in modern refinery tube furnaces, was investigated numerically. The influence of the fuel composition on convective heat transfer and the effect of substituting methane by other fuel types in furnaces designed to work on gas fuels were considered. It was shown that substitution of methane fuel by the other investigated gaseous fuels decreased the convective heat transfer in the furnace convective chamber. Convective heat transfer was influenced mainly by the fuel type.

Chemical and Petroleum Engineering. 2016;51(11-12):801-806
pages 801-806 views

Article

Evaluation of Critical Parameters of Neon Isotopes for Comparative Analysis of Various Methods for Separating Them

Bondarenko V.L., Nikiforov Y.V., Vorotyntsev V.B.

Abstract

Values of critical parameters of neon isotopes 20Ne and 22Ne are calculated. Approximate constants of the van-der-Waals, Berthelot, Dieterici I, and Redlich–Kwong equations of state are obtained. The data allow the adsorption isotherms for the neon isotopes on different adsorbents to be estimated by calculations.

Chemical and Petroleum Engineering. 2016;51(11-12):736-742
pages 736-742 views

Comparative Analysis of Various Adsorbents for Low-Temperature Separation of a 20Ne–22Ne Isotopic Mixture

Bondarenko V.L., Nikiforov Y.V., Vorotyntsev V.B.

Abstract

A method to obtain analytical expressions for evaluation of adsorption isotherms of neon isotopes at cryogenic temperatures is proposed. Adsorption isotherms of 20Ne and 22Ne on BAU activated carbon at 77 K are evaluated. The results allow the degree of influence of the pressure and composition of the 20Ne–22Ne isotopic mixture on the separation factor to be estimated.

Chemical and Petroleum Engineering. 2016;51(11-12):743-748
pages 743-748 views

Separation of Neon Isotopes by Stepwise Fractionation at 28 K

Bondarenko V.L., Shevich Y.A., Simonenko Y.M., Matveev E.V.

Abstract

Separation of Ne isotopes by fractionation at 28 K is studied. The number of transfer units in the upper and lower column sections is calculated with various loadings. Experimental characteristics of packed fractionation columns and examples of cascade systems constructed from them are given. A diagram of a cryogenic loop using a throttled high-pressure Ne cycle with intermediate N2 cooling is presented. The need and capability to create a pressure difference between the columns of the various steps were justified.

Chemical and Petroleum Engineering. 2016;51(11-12):749-754
pages 749-754 views

Simulation and Optimization of Amine Purification from Acidic Admixtures at Natural Gas Liquefaction Plants

Matveev S.A., Smorodin A.I.

Abstract

The capabilities of the Amines software module in the Aspen HYSYS software suite to simulate units for amine purification from acidic admixtures at natural gas plants are examined. A typical low-capacity natural gas liquefaction plant is used as an example to show that this software module can not only simulate but also optimize the design processing parameters of amine purification units.

Chemical and Petroleum Engineering. 2016;51(11-12):755-758
pages 755-758 views

Entropy Production and Exergy Loss During Mixing of Gases

Gareeva D.T., Lavrov N.A.

Abstract

Entropy and exergy analyses of losses during mixing of flows and volumes of gas are compared. It is shown that both methods give identical analytical expressions for an ideal gas. However, exergy analysis required more cumbersome mathematical transformations than entropy analysis in order to obtain a final result. An analysis of the expressions for determining the mixing losses always gives a positive result regardless of the temperature of the mixed flows or volumes. The final analytical expressions allow mixing losses to be determined. This is very important for thermodynamic analysis of low-temperature, especially cryogenic cycles.

Chemical and Petroleum Engineering. 2016;51(11-12):759-764
pages 759-764 views

Microcryogenic Gas Machines in Strategic Satellite Navigation, Surveillance, and Communications Systems

Arkharov I.A., Navasardyan E.S., Simakov M.V.

Abstract

The creation of advanced photodetectors as a single integrated electronic device is discussed. The main characteristics of low-capacity (0.5 W at ~77 K) Stirling microcryogenic gas refrigerating machines (MCGRM) produced by leading foreign and domestic manufacturers are presented. The use of Stirling MCGRM in cooling systems of satellite navigation and surveillance photodetectors is justified.

Chemical and Petroleum Engineering. 2016;51(11-12):765-770
pages 765-770 views

Mathematical Model of Cooling by Supercharged Gas

Zherdev A.A., Pushkarev A.V., Rossikhin N.A., Shakurov A.V.

Abstract

A method is proposed to improve the robot-assisted radical prostatectomy procedure by using a cooling gas of a controlled temperature. To determine the optimal gas flow rate and temperature values, it is necessary to carry out sample calculations taking into account the particular features of the processes taking place. To solve this problem, a mathematical model for the conjugate problem of convective heat transfer in the operational area and adjacent tissues was developed. The model reflects the unsteady cavity boundaries relating to the placement of the surgical incision. The mathematical model can be implemented in a computer program, which permits optimization of the gas parameters to provide the most favorable surgery conditions for the patient.

Chemical and Petroleum Engineering. 2016;51(11-12):771-777
pages 771-777 views

Using the Direct and Reverse Rankine Cycles to Create a Water-Cooling Chiller Running on Waste Heat

Kostenko A.A., Leonov V.P., Rosenoer T.M., Parkin A.N., Polikarpov A.V.

Abstract

This article presents the scheme for a Freon heat-recovery refrigeration unit developed on the basis of the forward and reverse Rankine cycle for cooling water. The arguments in favor of the possibility to create such small installations for cooling (5 kW at the temperature level of 5°C) are presented on the basis of turbomachinery (centripetal radial-axial turbines and centrifugal compressors). The calculated thermal coefficient for the installation is compared with the thermal coefficient of a single-stage absorption chiller running on an aqueous solution of lithium bromide.

Chemical and Petroleum Engineering. 2016;51(11-12):778-782
pages 778-782 views

Balancing Flow Rate Distribution Between Separate Devices in Plate-Fin Heat Exchanger Units

Matveev S.A., Smorodin A.I.

Abstract

The non-uniformity of flow rate distribution between separate devices of the plate-fin heat exchanger units working as a part of air separation plant, exceeding 2% of the nominal value, significantly reduces integral characteristics of the unit. Shortcomings of the method for regulating uniformity of flow rate distribution in the plate-fin heat exchanger units by means of regulating valves are considered. It is suggested to use a different approach allowing to avoid the use of expensive regulating valves and to specify the conditions to provide the required uniformity of flow rate distribution between separate heat exchangers already at the preliminary design stage.

Chemical and Petroleum Engineering. 2016;51(11-12):783-785
pages 783-785 views

Energy-Saving Multistage Filling of Adsorption Natural Gas Storage System

Strizhenov E.M., Zherdev A.A., Podchufarov A.A., Chugaev S.S., Kuznetsov R.A.

Abstract

A theoretical analysis of multistage (cascade) method of filling adsorption methane storage systems is made from the energy saving standpoint. It is demonstrated that multistage filling saves energy for gas compression substantially. The beneficial effect is much less if the compressed gas is filled in a cylinder without an adsorbent. The influence of the number of filling stages and the theoretical maximum of idealized filling with gradual elevation of compressor delivery pressure as the limiting case of multistage filling with an infinite number of stages are shown. The rated minimum energy consumption is 12% of the energy consumed for filling compressed gas in a system containing no adsorbent.

Chemical and Petroleum Engineering. 2016;51(11-12):786-792
pages 786-792 views

Determining the Fin Efficiency of a Single Perforated Plate of a Matrix Heat Exchanger in a Two-Dimensional Temperture Field

Shevich Y.A., Danilenko T.K., Shvets A.S.

Abstract

Results from theoretical and experimental investigations of the two-dimensional temperature field of a perforated plate that functions as the basic element of a heat-transfer surface in a matrix heat exchanger are presented. Experimental visualization of the temperature field by means of liquid crystals confirms that the assumptions adopted in the theoretical investigation are correct.

Chemical and Petroleum Engineering. 2016;51(11-12):793-798
pages 793-798 views

Estimation of Some Admissible Deviations from Design Size and Location of Structural Elements of Quick-Release Fasteners of Natural Gas Cleaning Filter Separators

Lisovskii O.N., Mitrofanov A.V., Kravtsov A.V., Men’shin A.B.

Abstract

An estimation of admissible deviations of size and location of structural elements of quick-release fasteners of natural gas cleaning filter separators from the design is given. A generalized computational model for analyzing stress-strain state and strength of cheeks of securing unit of quick-release fasteners with deviations is substantiated. Stress-strain and strength analysis revealed insufficient strength margin of the cheeks in the most stressed section. A method is proposed for strengthening the cheeks without disassembling the securing unit, which ensures the required strength margin in this section.

Chemical and Petroleum Engineering. 2016;51(11-12):807-811
pages 807-811 views

Capacity and Thermodynamic Nomograph for an Adsorption Methane Storage System

Strizhenov E.M., Zherdev A.A., Podchufarov A.A., Chugaev S.S., Kuznetsov R.A., Zhidkov D.A.

Abstract

General equations for calculation of the capacity and thermodynamic properties of adsorption methane storage systems were written. Experimental results for methane adsorption on AU-1 adsorbent were analyzed and plotted in the nomograph of capacity and thermodynamic properties of the adsorbent–adsorbate–gas adsorption system. Methods for graphical calculation of the processes occurring in the system were presented.

Chemical and Petroleum Engineering. 2016;51(11-12):812-818
pages 812-818 views

Determining the Expected Effective Characteristics of a Refrigerating Machine

Kalnin’ I.M., Krysanov K.S., Fadekov K.N.

Abstract

A new technique of creating a uniform designation of the points of the thermodynamic cycles of refrigerating machines in the state diagram of the cooling agent along with the computational equations of the parameters of the cycle are presented. The heat balances of the main and auxiliary devices of refrigerating machines are considered. A universal technique of determining the parameters of any thermodynamic cycle and a technique of determining the expected effective characteristics of refrigerating machines on the basis of the characteristics of the theoretical cycles are set forth. This makes it possible to perform a directed choice of designs and cycles for specified conditions.

Chemical and Petroleum Engineering. 2016;51(11-12):819-824
pages 819-824 views

On Modeling of the Blading Sections of Compressors with Dynamic Compression in Compression of Real Gases

Malyshev A.A., Pronin V.A.

Abstract

Similitude criteria of compression processes of real gases in the stages of compressors with dynamic compression are presented. A technique of compiling the thermal and caloric equations of state for gas mixtures and a technique of processing test data obtained in gaseodynamic tests are proposed.

Chemical and Petroleum Engineering. 2016;51(11-12):825-831
pages 825-831 views

The Economics of Cryosorption Pumping. The Practice of Using a Cryosorption Pump in an Industrial Pumping System

Amamchyan R.G., Goryachev M.A.

Abstract

It is shown that in the case of well-developed infrastructure for the use of liquid nitrogen the usage of nitrogen cryosorption pumps (NCP) is significantly more economical compared to the pumping means associated with the use of mechanical and steam jet pumps. The results of preliminary tests of the experimental sample NCP as part of a vacuum unit at the NPO Geliymash confirm the prospects of using NCPs in serial production of cryogenic vessels.

Chemical and Petroleum Engineering. 2016;51(11-12):832-834
pages 832-834 views

Heat Transfer of a Straight Flat Fin Surface Subjected to Low Temperature and Immersed in an Aqueous Medium with a Constant Temperature

Marinyuk B.T., Ugol’nikova M.A., Serenov I.I.

Abstract

An approximate analytical model is proposed to determine the thickness of the water ice layer on the surface of a straight flat fin as part of heat exchange equipment. This solution could be of interest for use in engineering calculations, in particular, in the design of water coolers, TNT evaporators, LNG gasifiers, etc.

Chemical and Petroleum Engineering. 2016;51(11-12):835-837
pages 835-837 views

Experience of Improving Rotor System Having Petal-Shaped Gas-Dynamic Bearings for Centrifugal Refrigeration Compressor

Ravikovich Y.A., Ermilov Y.I., Kholobtsev D.P., Sukhomlinov I.Y., Golovin M.V.

Abstract

The results of tests and improving Freon centrifugal refrigeration compressor having gas-dynamic bearings and cooling power up to 350 kW are reported. The problems relating to rotor balancing, start-stop durability of rotor and bearings, rotor dynamics, and the results of compressor tests in air and Freon are elucidated. The compressor was tested with two types of bearings: without and with goffered tapes. The best results were obtained with the second type. The potential for use of gas-dynamic bearings in centrifugal refrigeration compressors is confirmed.

Chemical and Petroleum Engineering. 2016;51(11-12):838-843
pages 838-843 views

Integrated Information Systems in the Management of the Chemical and Petrochemical Industries

Avrenyuk A.N., Khakimov T.A., Smol’nikov S.V., Popova E.V., Abutalipova E.M.

Abstract

The article is devoted to the development of an information system for the creation of an information environment for an industrial facility, including a large number of sites with complex relationships. All text and graphic information is summarized in a single structure in the development of an integrated information environment of the enterprise. Block diagrams were created of the elements necessary to include the information environment into the automated process of enterprise management.

Chemical and Petroleum Engineering. 2016;51(11-12):844-847
pages 844-847 views

Experience and Outlook for the Development of a Technology for Generation of the Profile of the Meshed Links of a Global Gear Pair by Rotational Turning

Sutyagin A.V., Mal’ko L.S., Trifanov I.V.

Abstract

A technique and results of mathematical modeling and numerical and physical experiments involving the generation of the profile of the helical surface of a concave worm by rotational turning of a multiblade tool with involute profile of the cutting element are presented. The efficiency of the production equipment used is improved and an increase in the performance of the process achieved.

Chemical and Petroleum Engineering. 2016;51(11-12):854-860
pages 854-860 views

Mechanized Welding of Copper Alloys with Low-Alloy Structural Steels

Pichuzhkin S.A., Chernobaev S.P., Vainerman A.A.

Abstract

As a result of experimental research, regimes are determined for mechanized argon-arc welding of copper alloys MNZh5-5, L90, and BrAMts9-2 with steels AB2 and 20, providing preparation of high quality joints during manufacture of chemical and petrochemical engineering objects.

Chemical and Petroleum Engineering. 2016;51(11-12):861-864
pages 861-864 views

Safety, Diagnosis, and Repair

Study of Features of the Change in Equipment Metal Properties Subject to Action of Hydrogen Sulfide-Containing Atmospheres

Sapun A.A., Zaryaev M.Y., Kravtsov A.V.

Abstract

New methods are provided for appraising equipment based on selection of macro- and micro-samples of heavily loaded metal and in contact with a working atmosphere, and subsequent analysis of its properties from experimental data. Use of these approaches makes it possible to appraise equipment without subsequent refurbishment, and to accomplish monitoring in order to evaluate equipment life according to static strength and brittle failure resistance criteria.

Chemical and Petroleum Engineering. 2016;51(11-12):848-853
pages 848-853 views