FIRST APPLICATION OF GRANULAR HIERARCHICAL ZEOLITES X IN THE SYNTHESIS OF ANILINE FROM NITROBENZENE BY HYDROGEN TRANSFER METHOD

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Abstract

The catalytic properties of FAU zeolites with different porosity (microporous Na-X and granulated micro-me-so-macroporous Na-Xh, K-Na-Xh and CuO/Na-Xh) in the synthesis of aniline by the reaction of nitrobenzene with 2-propanol were studied for the first time. It was found that the maximum yield of aniline of 94% with almost complete conversion of nitrobenzene is observed on the CuO/Na-Xh catalyst (300°C, 20 wt. % catalyst, nitrobenzene : alcohol = 1 : 16 mol/mol, 5 h). The high activity and selectivity of the CuO/Na-Xh zeolite are due to its hierarchical porous structure, as well as the presence of the maximum number of "weak" and "medium" acid sites. Zeolite K-Na-Xh demonstrates the lowest selectivity for aniline and an increase in side reactions of acetone condensation, which is apparently associated with a decrease in the number of acidic sites and the appearance of basic sites.

About the authors

S. V Bubennow

Institute of Petrochemistry and Catalysis Ufa Federal Research Center of the Russian Academy of Sciences (INK UFRC RAS)

Email: bubennov@list.ru
450075 Ufa, Russian Federation

A. S Artemieva

Institute of Petrochemistry and Catalysis Ufa Federal Research Center of the Russian Academy of Sciences (INK UFRC RAS)

450075 Ufa, Russian Federation

O. S Traukina

Institute of Petrochemistry and Catalysis Ufa Federal Research Center of the Russian Academy of Sciences (INK UFRC RAS)

450075 Ufa, Russian Federation

R. Z Kuvatova

Institute of Petrochemistry and Catalysis Ufa Federal Research Center of the Russian Academy of Sciences (INK UFRC RAS)

450075 Ufa, Russian Federation

N. A Philippova

Institute of Petrochemistry and Catalysis Ufa Federal Research Center of the Russian Academy of Sciences (INK UFRC RAS)

450075 Ufa, Russian Federation

N. G Grigorieva

Institute of Petrochemistry and Catalysis Ufa Federal Research Center of the Russian Academy of Sciences (INK UFRC RAS)

450075 Ufa, Russian Federation

B. I Kutepov

Institute of Petrochemistry and Catalysis Ufa Federal Research Center of the Russian Academy of Sciences (INK UFRC RAS)

450075 Ufa, Russian Federation

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