FIRST APPLICATION OF GRANULAR HIERARCHICAL ZEOLITES X IN THE SYNTHESIS OF ANILINE FROM NITROBENZENE BY HYDROGEN TRANSFER METHOD

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

The catalytic properties of FAU zeolites with different porosity (microporous Na-X and granulated micro-me-so-macroporous Na-Xh, K-Na-Xh and CuO/Na-Xh) in the synthesis of aniline by the reaction of nitrobenzene with 2-propanol were studied for the first time. It was found that the maximum yield of aniline of 94% with almost complete conversion of nitrobenzene is observed on the CuO/Na-Xh catalyst (300°C, 20 wt. % catalyst, nitrobenzene : alcohol = 1 : 16 mol/mol, 5 h). The high activity and selectivity of the CuO/Na-Xh zeolite are due to its hierarchical porous structure, as well as the presence of the maximum number of "weak" and "medium" acid sites. Zeolite K-Na-Xh demonstrates the lowest selectivity for aniline and an increase in side reactions of acetone condensation, which is apparently associated with a decrease in the number of acidic sites and the appearance of basic sites.

Авторлар туралы

S. Bubennow

Institute of Petrochemistry and Catalysis Ufa Federal Research Center of the Russian Academy of Sciences (INK UFRC RAS)

Email: bubennov@list.ru
450075 Ufa, Russian Federation

A. Artemieva

Institute of Petrochemistry and Catalysis Ufa Federal Research Center of the Russian Academy of Sciences (INK UFRC RAS)

450075 Ufa, Russian Federation

O. Traukina

Institute of Petrochemistry and Catalysis Ufa Federal Research Center of the Russian Academy of Sciences (INK UFRC RAS)

450075 Ufa, Russian Federation

R. Kuvatova

Institute of Petrochemistry and Catalysis Ufa Federal Research Center of the Russian Academy of Sciences (INK UFRC RAS)

450075 Ufa, Russian Federation

N. Philippova

Institute of Petrochemistry and Catalysis Ufa Federal Research Center of the Russian Academy of Sciences (INK UFRC RAS)

450075 Ufa, Russian Federation

N. Grigorieva

Institute of Petrochemistry and Catalysis Ufa Federal Research Center of the Russian Academy of Sciences (INK UFRC RAS)

450075 Ufa, Russian Federation

B. Kutepov

Institute of Petrochemistry and Catalysis Ufa Federal Research Center of the Russian Academy of Sciences (INK UFRC RAS)

450075 Ufa, Russian Federation

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