Email this article Phenylhydrosilocane as a source of silatranylium cations
- Authors: Kochina T.A.1, Avrorin V.V.2, Fundamensky V.S.3, Ignatyev I.S.2
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Affiliations:
- I. V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences
- St. Petersburg State University
- St. Petersburg State Institute of Technology, Technical University
- Issue: Vol 65, No 4 (2016)
- Pages: 1047-1052
- Section: Full Articles
- URL: https://ogarev-online.ru/1066-5285/article/view/237847
- DOI: https://doi.org/10.1007/s11172-016-1411-2
- ID: 237847
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Abstract
Quantum chemical calculations were used for comparative analysis of the cations of the atrane structure [M(OCH2CH2)3N]+ (M = Si or Ge) with classic three-coordinate cations R3M+ of Group 14 elements. The possibility of nuclear chemical generation of atranylium cations in the condensed phase was experimentally demonstrated with silatranylium ions as examples.
About the authors
T. A. Kochina
I. V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: t-kochina@mail.ru
Russian Federation, 2 nab. Makarova, St. Petersburg, 199034
V. V. Avrorin
St. Petersburg State University
Email: t-kochina@mail.ru
Russian Federation, 7/9 Universitetskaya nab., St. Petersburg, 198504
V. S. Fundamensky
St. Petersburg State Institute of Technology, Technical University
Email: t-kochina@mail.ru
Russian Federation, 26 Moskovskii prosp., St. Petersburg, 190013
I. S. Ignatyev
St. Petersburg State University
Email: t-kochina@mail.ru
Russian Federation, 7/9 Universitetskaya nab., St. Petersburg, 198504
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