Phenylhydrosilocane as a source of silatranylium cations
- Авторы: Kochina T.A.1, Avrorin V.V.2, Fundamensky V.S.3, Ignatyev I.S.2
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Учреждения:
- I. V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences
- St. Petersburg State University
- St. Petersburg State Institute of Technology, Technical University
- Выпуск: Том 65, № 4 (2016)
- Страницы: 1047-1052
- Раздел: Full Articles
- URL: https://ogarev-online.ru/1066-5285/article/view/237847
- DOI: https://doi.org/10.1007/s11172-016-1411-2
- ID: 237847
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Аннотация
Quantum chemical calculations were used for comparative analysis of the cations of the atrane structure [M(OCH2CH2)3N]+ (M = Si or Ge) with classic three-coordinate cations R3M+ of Group 14 elements. The possibility of nuclear chemical generation of atranylium cations in the condensed phase was experimentally demonstrated with silatranylium ions as examples.
Об авторах
T. Kochina
I. V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: t-kochina@mail.ru
Россия, 2 nab. Makarova, St. Petersburg, 199034
V. Avrorin
St. Petersburg State University
Email: t-kochina@mail.ru
Россия, 7/9 Universitetskaya nab., St. Petersburg, 198504
V. Fundamensky
St. Petersburg State Institute of Technology, Technical University
Email: t-kochina@mail.ru
Россия, 26 Moskovskii prosp., St. Petersburg, 190013
I. Ignatyev
St. Petersburg State University
Email: t-kochina@mail.ru
Россия, 7/9 Universitetskaya nab., St. Petersburg, 198504
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