Enviar artigo por via de e-mail Phenylhydrosilocane as a source of silatranylium cations
- Autores: Kochina T.A.1, Avrorin V.V.2, Fundamensky V.S.3, Ignatyev I.S.2
-
Afiliações:
- I. V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences
- St. Petersburg State University
- St. Petersburg State Institute of Technology, Technical University
- Edição: Volume 65, Nº 4 (2016)
- Páginas: 1047-1052
- Seção: Full Articles
- URL: https://ogarev-online.ru/1066-5285/article/view/237847
- DOI: https://doi.org/10.1007/s11172-016-1411-2
- ID: 237847
Citar
Acesso aberto
Acesso está concedido
Somente assinantes
Resumo
Quantum chemical calculations were used for comparative analysis of the cations of the atrane structure [M(OCH2CH2)3N]+ (M = Si or Ge) with classic three-coordinate cations R3M+ of Group 14 elements. The possibility of nuclear chemical generation of atranylium cations in the condensed phase was experimentally demonstrated with silatranylium ions as examples.
Sobre autores
T. Kochina
I. V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences
Autor responsável pela correspondência
Email: t-kochina@mail.ru
Rússia, 2 nab. Makarova, St. Petersburg, 199034
V. Avrorin
St. Petersburg State University
Email: t-kochina@mail.ru
Rússia, 7/9 Universitetskaya nab., St. Petersburg, 198504
V. Fundamensky
St. Petersburg State Institute of Technology, Technical University
Email: t-kochina@mail.ru
Rússia, 26 Moskovskii prosp., St. Petersburg, 190013
I. Ignatyev
St. Petersburg State University
Email: t-kochina@mail.ru
Rússia, 7/9 Universitetskaya nab., St. Petersburg, 198504
Arquivos suplementares
