Peculiarities of EPR in polycrystalline solid solutions Zn0.95Fe0.05O with different particles morphology: The role of intrinsic defects in formation of magnetic properties


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Abstract

Single-phase polycrystalline samples of Zn0.95Fe0.05O having the wurtzite structure and different morphology of particles were obtained using precursor technologies. It was found by electron spin resonance that iron enters the ZnO crystal lattice in the Fe3+ charge state. Magnetic studies revealed that the obtained samples show weak ferromagnetic properties at 300 K. A correlation between the number of oxygen vacancies and the degree of ferromagnetic ordering was found.

About the authors

M. A. Melkozerova

Institute of Solid-State Chemistry, Ural Branch

Author for correspondence.
Email: melkozerova@yandex.ru
Russian Federation, Yekaterinburg, 620990

O. I. Gyrdasova

Institute of Solid-State Chemistry, Ural Branch

Email: melkozerova@yandex.ru
Russian Federation, Yekaterinburg, 620990

T. V. D’yachkova

Institute of Solid-State Chemistry, Ural Branch

Email: melkozerova@yandex.ru
Russian Federation, Yekaterinburg, 620990

A. P. Tyutyunnik

Institute of Solid-State Chemistry, Ural Branch

Email: melkozerova@yandex.ru
Russian Federation, Yekaterinburg, 620990

V. V. Bannikov

Institute of Solid-State Chemistry, Ural Branch

Email: melkozerova@yandex.ru
Russian Federation, Yekaterinburg, 620990

E. V. Zabolotskaya

Institute of Solid-State Chemistry, Ural Branch

Email: melkozerova@yandex.ru
Russian Federation, Yekaterinburg, 620990

V. V. Marchenkov

Mikheev Institute of Metal Physics, Ural Branch; Ural Federal University named after the first President of Russia B.N. Yeltsin

Email: melkozerova@yandex.ru
Russian Federation, Yekaterinburg, 620990; Yekaterinburg, 620002

Yu. A. Perevozchikova

Mikheev Institute of Metal Physics, Ural Branch

Email: melkozerova@yandex.ru
Russian Federation, Yekaterinburg, 620990

F. Sauerzopf

TU Wien Atominstitut

Email: melkozerova@yandex.ru
Austria, Vienna, 1020

V. N. Krasil’nikov

Institute of Solid-State Chemistry, Ural Branch

Email: melkozerova@yandex.ru
Russian Federation, Yekaterinburg, 620990

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