High-temperature heat capacity of samarium and erbium titanates with pyrochlore structure


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Resumo

Titanates Sm2Ti2O7 and Er2Ti2O7 with pyrochlore structure have been prepared by solid-phase synthesis in air from stoichiometric Sm2O3 (Er2O3)–TiO2 mixtures sequentially at 1673 and 1773 K. Hightemperature heat capacity of the oxide compounds has been determined by differential scanning calorimetry. Their thermodynamic properties have been calculated from experimental temperature dependence Cp = f(T).

Sobre autores

L. Denisova

School of Non-Ferrous Metals and Material Science

Autor responsável pela correspondência
Email: antluba@mail.ru
Rússia, Krasnoyarsk, 660025

L. Chumilina

School of Non-Ferrous Metals and Material Science

Email: antluba@mail.ru
Rússia, Krasnoyarsk, 660025

V. Denisov

School of Non-Ferrous Metals and Material Science

Email: antluba@mail.ru
Rússia, Krasnoyarsk, 660025

V. Ryabov

Institute of Metallurgy, Ural Branch

Email: antluba@mail.ru
Rússia, Yekaterinburg, 620219

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