Cointercalation of titanium dichalcogenides with transition metals and copper


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Сointerсalated materials are studied, obtained by introducing copper into a TiSe2 lattice preintercalated with transition metals M = Mn, Fe, Co, or Ni. The analysis of the state of cointercalated systems at 950°C shows that copper reduces manganese and iron, but it is incapable of reducing cobalt or nickel. To explain the results, the values of the binding energy of hybrid states M3d/Ti3d are compared.

Sobre autores

A. Titov

Institute of Metal Physics, Ural Branch

Email: antitov@mail.ru
Rússia, Yekaterinburg, 620990

A. Titov

Institute of Metal Physics, Ural Branch; Ural Federal University

Autor responsável pela correspondência
Email: antitov@mail.ru
Rússia, Yekaterinburg, 620990; Yekaterinburg, 620002

S. Titova

Institute of Metallurgy, Ural Branch

Email: antitov@mail.ru
Rússia, Yekaterinburg, 620016

S. Pryanichnikov

Institute of Metallurgy, Ural Branch

Email: antitov@mail.ru
Rússia, Yekaterinburg, 620016

D. Chezganov

Ural Federal University

Email: antitov@mail.ru
Rússia, Yekaterinburg, 620002

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