Email this article Cointercalation of titanium dichalcogenides with transition metals and copper
- Authors: Titov A.A.1, Titov A.N.1,2, Titova S.G.3, Pryanichnikov S.V.3, Chezganov D.S.2
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Affiliations:
- Institute of Metal Physics, Ural Branch
- Ural Federal University
- Institute of Metallurgy, Ural Branch
- Issue: Vol 59, No 1 (2017)
- Pages: 145-150
- Section: Phase Transitions
- URL: https://ogarev-online.ru/1063-7834/article/view/199538
- DOI: https://doi.org/10.1134/S1063783417010346
- ID: 199538
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Abstract
Сointerсalated materials are studied, obtained by introducing copper into a TiSe2 lattice preintercalated with transition metals M = Mn, Fe, Co, or Ni. The analysis of the state of cointercalated systems at 950°C shows that copper reduces manganese and iron, but it is incapable of reducing cobalt or nickel. To explain the results, the values of the binding energy of hybrid states M3d/Ti3d are compared.
About the authors
A. A. Titov
Institute of Metal Physics, Ural Branch
Email: antitov@mail.ru
Russian Federation, Yekaterinburg, 620990
A. N. Titov
Institute of Metal Physics, Ural Branch; Ural Federal University
Author for correspondence.
Email: antitov@mail.ru
Russian Federation, Yekaterinburg, 620990; Yekaterinburg, 620002
S. G. Titova
Institute of Metallurgy, Ural Branch
Email: antitov@mail.ru
Russian Federation, Yekaterinburg, 620016
S. V. Pryanichnikov
Institute of Metallurgy, Ural Branch
Email: antitov@mail.ru
Russian Federation, Yekaterinburg, 620016
D. S. Chezganov
Ural Federal University
Email: antitov@mail.ru
Russian Federation, Yekaterinburg, 620002
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