


Vol 487, No 2 (2019)
- Year: 2019
- Articles: 31
- URL: https://ogarev-online.ru/1028-334X/issue/view/12259
Geology
Change in the Geodynamic Settings in the Pacific‒Eurasia Transition Zone at the End of the Early Cretaceous
Abstract
An attempt to provide a new explanation for the change in the geodynamic regime in the Early Cretaceous is presented below. It accounts for data on a number of global geodynamic characteristics in the range of 200–65 Ma reflecting processes both deep in the Earth and on the surface, and seemingly directly unrelated to the formation of a transform margin in Eastern Asia. It has been found that the geodynamic regime changed in the range of 115‒110 Ma.



The Late Vendian Basement within the Limits of the Blyb Metamorphic Complex, Peredovoi Range of the Greater Caucasus
Abstract
New data are presented concerning the age and relationships with the overlapping rocks of the Balkan massif of quartz diorites located in the central part of the Blyb metamorphic complex of the Peredovoi Range of the Greater Caucasus in the Malaya Laba River basin. For the first time, using modern geochronological methods, it is shown that the Balkan massif is a Precambrian formation. An estimate of the age of the rocks of the Balkan massif using the SHRIMP II method for three U–Pb datings gives an interval of 549 ± 7.4 to 574.1 ± 6.7 Ma. A new interpretation of the structure of the basement of the Peredovoi Range is suggested, according to which the rocks of the Late Vendian foundation are exposed in a tectonic window and overlapped by Middle Paleozoic metamorphic rocks of the Armov cover, first identified by a combination of geological features. The lower boundary of the cover is characterized by a sharp change in composition and a change in the orientation of planar textures. On the border with the Armovka cover, there is a thick blastomilonite unit.



Two New Localities of Mesozoic Mammals in Russia (Krasnoyarsk Territory, Lower Cretaceous)
Abstract
Two new localities of Mesozoic mammals have been discovered: Bol’shoi Ilek and the Berezovaya River (Russia, Krasnoyarsk Territory, Lower Cretaceous, Ilek Formation). Bol’shoi Ilek locality has yielded an edentulous fragment of the maxillary of Docodonta indet. A fragment of dentary without teeth attributed to Mammalia indet. (presumably eutriconodontan or symmetrodontan) has been found at the Berezovaya River locality. These new localities fill the geographical gap between previously known mammalian sites of the Ilek Formation in the basins of the Kiya and Bol’shoi Kemchug rivers.



Middle Paleozoic Rhyolite of the Gorny and Rudny Altai: Geochronology and Composition
Abstract
The paper reports the results of geological, geochemical, and isotope–geochronological studies of subvolcanic rhyolites of NW Gorny Altai and Rudny Altai, which belong to the large Hercynian volcanic systems: Altai-Minusa and Altai–Salair, respectively. U–Pb zircon dating revealed two age groups: ~410–405 and 390–381 Ma. The isotope–geochemical characteristics of the rhyolites demonstrate high εNd(Т) from +2.6 to 6.0 with relatively young model ages T(DM) = 851–966 Ma in Rudny Altai and older model ages, up to 1266 Ma, in NW Gorny Altai. The rhyolites show transitional geochemical signatures between within-plate and island-arc felsic magmas. The results obtained are consistent with two-stage evolution of volcanism and its migration from the continent to the ocean.



Relationship between Radon and the Tectonic Activity of Faults in Central Mongolia
Abstract
The relationship between radon and the tectonic activity of faults for two geodynamically active regions of Central Mongolia is shown with account for the influence of individual characteristics of the radon field. As a whole, the radon activity of the faults increases with an increasing contribution of extension to the dynamic environment of their formation, with increasing seismic activity, and near concentrated faults of the late stages of evolution in comparison with the wide zones of fractures at the early stages of the formation of the internal structure. The studied patterns should provide an increase in the efficiency of application of radon surveys in investigation of the seismic hazard of faults in the Earth’s crust.



A Jurassic Anoxic Event in the Pacific Based on Data from the West Kamchatka–Asian Region
Abstract
Based on allochthonous complexes of the Asian–West Kamchatka region, an Early Jurassic (Sinemurian–Toarcian) oceanic anoxic event (J-OAE) in the Nothern Pacific has been revealed for the first time. This event is indicated by sulfide-containing bituminous black cherts that accumulated under euxinic conditions of deep oceanic basins. The anoxia gradually weakened to end completely by the beginning of the Late Jurassic, when hematite jaspers began to accumulate in the aerated water mass. The J-OAE in the Pacific was synchronous to the global warming stage caused by worldwide magmatism; gas-hydrothermal contribution induced a euxinic regime of oceanic water, a change in the carbon cycle, and the change in the taxonomy of radiolarians revealed by Hori [3]. The J-OAE of the Pacific expands the time interval of the known T-OAE and is also supported by the data from other oceanic basins of the world.



Cover of the Last Glaciation Deposits in the Eastern Barents Sea: Specificity of Composition, Thickness Distribution, Immensity, and Peculiarity of Structural Forms
Abstract
Analysis of the data of seismoacoustic investigations and geotechnical drilling in the Eastern Barents Sea has shown the following. The cover of the Upper Weichselian glacial deposits spreads regionally. It represents a seismostratigraphic complex (SSC) SSC III, which occurs unconformably on the Mesozoic deposits and partly on the Lower Weichselian morain (SSC V) and is overlain unconformably by the Late Glacial glaciomarine (SSC II)–Holocene marine (SSC I) sediments. SSC III consists of two seismofacies (SF). The dominant SF III-C is represented almost entirely by ordinary moraine, and SF III-T is represented by M-moraine. The occurrence of these moraines almost totally determines the distribution of the SSC III thicknesses. The ordinary moraine thickness varies from <10 m to 10–25 m. The M-moraine forms positive accumulation bodies huge in plan with a thickness of >25 m, reaching 50–75 m. The Upper Weichselian deposit cover has also exhibited other immense structural morphological elements: end moraines (a giant form has been recorded) and powerful subglacial cuts representing a unique unburied analog of so-called tunnel valleys. The features of the structure, composition, and thicknesses of the SSC III deposit cover are determined by the specific character of the development of Last Glaciation in the region.



New Data on the Age of Metamorphic Rocks from the Granite-greenstone Ruker Terrane (Southern Prince Charlies Mountains, East Antarctica)
Abstract
This work presents results of isotope studies of primary igneous and sedimentary rocks of Mawson and Menzies series from the southern Prince Charles Mountains, East Antarctica. The data obtained show that the crystallization of the protolith of Mawson orthogneisses occurred at 3164.2 ± 9.2--3163.2 ± 7.8 Ma ago. The Mawson orthogneisses were the basement for accumulation of the deposits of the Menzies series. The maximum time of the deposition is estimated to be in a range of 3.0--3.1 Ga. The protolith of Menzies sedimentary deposits contains an admixture of the Paleoarchean material.



Finding of Refractory Inclusions in the North Kolchim Meteorite (H3)
Abstract
For the first time among Russian meteorites, refractory forsterite-rich inclusions are determined in the North Kolchim meteorite (H3). Forsterite-rich inclusions are found mainly in carbonaceous chondrites; they are extremely rare in ordinary chondrites. These inclusions are considered by most researchers as one of the earliest formations in the Solar System. The inclusions of the North Kolchim meteorite are composed of high-magnesia forsterite (FeO 0.4–2%), which contains higher CaO (0.5–1%) and Al2O3 contents (up to 0.4%) and is depleted in MnO. In some places, forsterite is found in intergrowths with high-magnesia enstatite (FeO of 0.5–2.5%) also containing CaO impurities of up to 0.5%, Al2O3 of up to 1.5%, and MnO below the detection limits. A characteristic feature of forsterite-rich inclusions is that, unlike chondrules, they are mostly represented by acute-angled fragments, and that is probably due to their relatively frequent collisions.



New U–Pb Ages of the Volcano–Plutonic Association of the Oloi Belt (Alazeya–Oloi Folded System, Western Chukotka)
Abstract
The Egdygkych hypabyssal rocks of the Nichan and Vuknei massifs, as well as the host volcanites and tuffs of the Oloi volcanic belt of the Alazeya–Oloi folded system have been dated by U–Pb (SIMS and LA–ICP–MS). The obtained ages of the Egdygkych complex correspond to the Early Cretaceous (Berriasian–Valanginian), while those of their host rocks range from the Late Jurassic (Tithonian) to the beginning of the Early Cretaceous (Berriasian). These new U–Pb geochronological data confidently suggest a unity of the volcanic–plutonic association of the Late Jurassic (Tithonian)–Early Cretaceous (Berriasian–Valanginian) age of the Oloi volcanic belt. The data obtained refine the age range of Au–Mo–Cu ores confined to the contacts between the Egdygkych complex rocks and host volcano-sedimentary deposits or contacts of individual intrusive phases within the complex.



Geochemistry
Comparative Geochemical Characteristics and Genesis of Large Polyphase Plutons in the Cores and on the Periphery of the Mongol–Okhotsk Fold Belt Magmatic Areas of Different Ages
Abstract
The early Mesozoic Baga-Khentei pluton is a part of the Daurian–Khentei batholite that was formed under the impact of the Mongolian plume on the lower horizons of the continental crust in the collision compression zone that appeared during closing of the Mongol–Okhotsk Ocean. Mantle and crustal melt sources were involved in the formation of the batholith and its margins. The Ikh-Narotin-Khid massif tends to the boundary of the rift region on the periphery of the Late Mesozoic area. The petro-geochemical similarity of its rocks to the composition of host gneisses suggests that the latter belong to the most likely substrate in the formation of palingenic granitoids of the calc-alkaline series. The differences in the rock compositions of large plutons are shown in minor differentiation of the Baga-Khentei massif, which is likely to be determined by the anatexis conditions and the subsequent formation of melts in the collision compression setting, while the granites of the Ikh-Narotin-Khid massif were formed under extension, which favored deep differentiation of magmatic melts.



A New Geochemical Criterion for Rare-Metal Mineralization of High-Alkaliс Magmas (Lovozero Deposit, Kola Peninsula)
Abstract
Detailed studies have shown that a change in the eudialyte occurrence forms (and the moment of its crystallization) is a new geochemical criterion for rare metal ore content in alkalic magmas (eudialyte ores). A new principle of the presence of ores in alkalic magmas has been formulated: a prerequisite for the formation of an ore deposit is early saturation of alkalic magmas with an ore mineral. If the ore component concentration is significantly lower than the cotectic (saturation), then melt saturation and crystallization of an ore mineral will take place at later stages of rock formation in a small volume of the interstitial melt, when the phenomena of convective‒gravity differentiation and segregation of mineral phases in the form of ore deposits are hampered. This leads to dispersion of the ore components in the form of xenomorphic grains of accessory minerals. Rocks of the differentiated complex (lower zone of the Lovozero deposit) and rocks of the Khibiny massif contain xenomorphic eudialyte and are not promising for eudialyte ores. Eudialyte deposits are associated with the upper zone of the Lovozero intrusion where euhedral early eudialyte occurs. The initial magma is saturated with eudialyte after crystallization of about 80% of the intrusion. The proposed criterion is applicable to the largest alkalic massifs in the world. The Ilimaussaq massif (Greenland), the rocks of which contain early crystallized, euhedral eudialyte, hosts a superlarge eudialyte ore deposit. Unlike the Khibiny massif and the Pilanesberg alkalic complex, the rocks of which contain late xenomorphic eudialyte, this massif has no deposits of this type.



A Find of Coesite in Diamond-Bearing Kyanite Eclogite from the Udachnaya Kimberlite Pipe, Siberian Craton
Abstract
A find of coesite in a kyanite graphite–diamond-bearing eclogite xenolith from the Udachnaya–Vostochnaya kimberlite pipe is described in this paper. The coesite relics were found in intensely fractured garnet indicating some influence of the kimberlite melt, which is supported by the typical secondary mineral assemblage around this inclusion. These data indicate that shallower diamond-free coesite-grade rocks (2.7 GPa) underwent metamorphism distinct from diamond-bearing coesite eclogites (≥4 GPa). The metasomatic alteration of rock as a result of the C–O–H fluid-rock interaction during diamond crystallization may be another possible reason for the absence of coesite in diamond-bearing xenoliths.



Synthetic Gold Chalcogenides in the Au–Te–Se–S System and Their Natural Analogs
Abstract
Quaternary chalcogenides of AuX (AuTe0.7Se0.2S0.1), Au3X10 (Au3Te6Se3S, Au3Te6Se2.5S1.5), and AuX2 (AuTe1.8Se0.2, AuTe1.8Se0.1S0.1) composition were synthesized for the first time in the Au‒Te‒Se‒S system, where Te ≥ Se + S. They are produced by dry synthesis upon heating a mixture of elementary substances with compositions of AuTe0.666Se0.167S0.167 (X/Au = 1, X = Σ(Te + Se + S)), AuTeSe0.5S0.5 (X/Au = 2), AuTe2Se1.125S0.375, AuTe2Se0.75S0.75 (X/Au = 3.5), and AuTe2.5SeS0.5 (X/Au = 4) in vacuum quartz ampoules from 25–700°C and annealing at 400°C. According to XRD, the synthetic Au chalcogenides of AuTe1.8(Se,S)0.2 composition correspond to calaverite (α-AuTe2). The unidentified XRD peaks belong to AuX and Au3X10. They are synthetic analogs of previously unknown natural compounds, which were found in the Gaching area of the Maletoivayam ore field (Central Kamchatka volcanic belt). The compositions of natural phases span the following ranges: Au0.99–1.00Te0.70–0.71Se0.25–0.27S0.03–0.06 and Au2.91–3.08Te5.85–6.06Se1.57–3.66S2.63–0.44. The Raman spectra of synthetic and natural Au chalcogendies close in composition are identical.



Role of Desorption Processes in Transformation of Dissolved Barium Runoff in the Mixing Zone of River Waters and Seawaters: Experimental Modeling Data
Abstract
The sorption–desorption barium balance during interaction between silt–sand terrigenous material and salty seawater is determined experimentally. The mean value of barium desorption in the mixing zone of river waters and seawaters is 13 μg/g, making up an additional supply of 80 000 tons of Ba per year, or 8.6% of its runoff to the ocean, without runoff transformation at the river–sea geochemical barrier being taking into account. The obtained estimate of the role played by desorption in transformation of dissolved barium runoff agrees, in terms of the order of value, with the data of real observations for the majority of mouth zones of the world rivers.



Garnet U–Pb Age of Skarns from Dashkesan Deposit (Lesser Caucasus)
Abstract
The results of the U–Pb geochronological study of garnet from scarns of the Dashkesan deposit are reported. The first “direct” estimate of the age of the skarn formation and ore genesis for this deposit (147 ± 2 Ma) is obtained. The possibility of using the U–Pb garnet system to obtain estimates of the scarns age is shown.



Synthesis of New Polytypic Modifications of Fe7C3 at 5.5 GPa
Abstract
The results of experimental synthesis of carbide Fe7C3 at 5.5 GPa are presented. It is found that carbide Fe3C and several polytypes of carbide Fe7C3 are formed along with diamond during cooling of the system. It is considered that the Fe7C3 phase is a component of the Earth’s inner core. Our results indicate that polytypic carbide modifications could have been formed under natural conditions at relatively low pressures during differentiation of the Earth.



REE Geochemistry and Mineralogy in Ores of the Talgan Cu–Zn Massive Sulfide Deposit, Southern Urals
Abstract
The high REE concentrations (57.23–561.2 ppm) in thin-layered sulfide ores of the Talgan Cu–Zn massive sulfide deposit (Southern Urals) are related to the presence of REE minerals: galgenbergite, parisite, bastnaesite, synchysite, and xenotime, which were found in massive sulfide deposits of the Urals for the first time. These minerals occur in a quartz–carbonate–chlorite matrix of sulfide layers, pyrite nodules, and in the form of sub- and euhedral crystals. The chondrite-normalized REE distribution spectra characterized by the enrichment in LREEs relative to HREEs and the presence of weak negative Ce and positive Eu anomalies. The LREE concentrations decrease by an order of magnitude, and the LREE and HREE concentrations become similar with a decrease in the amount of hyaloclastic material in the sulfide layers. The carbonate–hyaloclastic material mixed with ore fragments during the formation of layered sulfide ores was considered to be a source of matter for the formation of REE minerals.



First Data on Molybdenite and Its Primary Sources in Pay-Khoy (Nenets Autonomous District): Mineralogy, Geochemistry, and Raman Spectroscopy
Abstract
The first data on five primary molybdenite sources within the gabbro-dolerite complex of Pay-Khoy (Pay-Khoy Ridge, Yugra Peninsula, Russia) are presented. The mineral is extended areally in Devonian ore-bearing gabbro-dolerites, contact rocks, and quartz veins. This paper considers the mineralogical–geochemical features of molybdenite, its occurrence, the composition of host rocks, and spectroscopic studies.



Geography
Terrain Morphometry and Mudflow Features in the Northern Slope of the Great Caucasus
Abstract
Morphometric terrain parameters such as slope angles and altitudes make a considerable contribution to the features of mudflows. In order to assess the contribution of these factors, this study analyzes their characteristics in the Western, Central, and Eastern Caucasus on the basis of an original digital terrain model. The average slope angles in the Western Caucasus are higher by 0.5° than those in the Central and Eastern Caucasus, thus contributing to more active mudflow. On the other hand, the Western Caucasus is distinguished by lower altitude differences. From the standpoint of this factor, the Central Caucasus is the most mudflow hazardous. Hence, the absolute altitude distribution and high forestation neutralize the factor of more significant slope angles and ensure the less considerable mudflow danger in the Western Caucasus relative to the Central and Eastern Caucasus.



Peculiarities of the Settling Temperature in the Upper Water Layer of the Black Sea during Invasions of Cold Air
Abstract
Based on the results of drifter observations in the western Black Sea, it is shown that winter intrusions of cold air (ICAs) are accompanied by wind of 10 m/s in speed and by a decrease in temperature of the upper mixed layer (UML) by 0.1–0.2°C per day. Notably, the seasonal thermocline (ST) and cold intermediate water deepen, whereas after the ICA stops, these layers ascend to lower depths, causing settling of the lower temperature of the UML (while higher than the one relative to the period before the ICA) in the layer beneath ST. This process of the upper layer mixing is explained by the role played by mesoscale anticyclones.



An Integrated Mathematical Model of the Large Marine Ecosystem of the Barents Sea and the White Sea as a Tool for Assessing Natural Risks and Efficient Use of Biological Resources
Abstract
An integrated mathematical model of the Barents Sea and White Sea Large Marine Ecosystem proposed as a tool for assessing natural risks and efficient use of the biological resources is considered. The model includes the following main blocks (modules) of (а) oceanographic variation and biological productivity; (b) trophodynamics and fishery management; (c) environmental and biota pollution; (d) social and economic development; and (e) assessment of ecological risks from marine activities. The results of using the integrated model for assessing hydrological variability, long-term dynamics of ecosystem productivity, and assessment of fishing pressure on the most important fishery species of the Barents Sea are presented. A new scheme of zoning of the Barents Sea area performed under the supervision of Academician G.G. Matishov with respect to geomorphological and hydrological factors is proposed. A comparative scheme of distribution of the estimated gross primary production in the Barents Sea area in the second half of the twentieth century and in the 2010s is presented. The energy balance of the Barents Sea ecosystem in the late 1900s and early 2000s is calculated by the model of trophodynamics. The necessity of using mathematical models of the ecosystem instead of single-species models during the calculation of fishing pressure on the populations is suggested. To estimate fishing mortality, it is necessary to take into account not only spatial effects related to the features of a fish life cycle and distribution of fishing pressure, but also the impact of climate factors and ecosystem interactions. The use of recent information technologies both in the field of accumulation and analysis of the primary data and in the area of their subsequent generalization for the diagnosis of past changes makes it possible to understand better the possible consequences of the existing plans for developing and use of available natural resources for the Barents Sea and White Sea LME based on the experience (sometimes negative) of recent years and expected climate changes.



High-Resolution Oxygen Isotope and Deuterium Diagrams for Ice Wedges of the Batagai Yedoma, Northern Central Yakutia
Abstract
The stable oxygen and hydrogen isotope composition of Late Pleistocene syngenetic ice wedges of Batagai yedoma are studied, and detailed isotope diagrams are obtained. The reconstructed mean January paleotemperature is lower than –51°С, which completely confirms the validity of the paleotemperature maps made earlier for the period of 30–25 ka BP where the location of the Batagai section within the isotherm of –48°C.



Change in the Hydrological Regime of Siberian Rivers as an Indicator of Changes in Cryological Conditions
Abstract
A new phenomenon, an increase in the winter and early spring streamflow of Siberian rivers, has been studied. Based on the assumption that the increased discharge may be due to permafrost degradation in the river basins, the rate of degradation of the different zones of permafrost distribution is estimated by modeling. A mathematical model that takes into account the typification of the permafrost zones and reflects the dependence of the streamflow on the cryological conditions of the drainage basins has shown rapid degradation of sporadic permafrost and expansion of discontinuous permafrost owing to the intense transition of continuous permafrost to this state.



Climatology and Interannual Movements of Upper-Level Frontal Zones in the Middle Troposphere of the Northern Hemisphere
Abstract
Based on the use of an objective methodology that takes into account the local values of the geopotential gradients, the long-term average position of the upper-level frontal zones (UFZs) in the middle troposphere for the Northern Hemisphere over the period of 1948–2014 is calculated for the first time. The procedure for determining UFZs has consisted in estimation of the monthly-average fields of the module of a horizontal geopotential gradient by the approximation of derivatives using the central difference method. Based on the obtained fields of geopotential gradients, the local highs were identified and the positions of the upper-level frontal zones in different seasons were found. The updated climatology of UFZs significantly refines the earlier information, specifying the position of UFZs and identifying, e.g., UFZs that exist only in particular seasons. The estimates of the interannual movements of HAVZs are also obtained for the first time, which makes it possible to analyze the mechanisms of the observed climate variability in different regions of the Earth.



Oceanology
The First Colorimetric Characteristic of Bottom Sediments from the Chukchi Sea
Abstract
The quantitative characteristics of the bottom sediment color of the Chukchi Sea is presented. The correlation relationships with the contents of grain-size fractions, chemical elements, and biogenic components are analyzed. The diagenetic factor influence is considered. The prospects of the colorimetric index such as saturation S is noted in the matter of lithostratigraphy.



Horizontal Flows of Sedimentary Matter in the Coastal Zones of the Barents and White Seas
Abstract



Features of Sound Propagation in the Presence of Bubble Clouds in the Perturbed Surface Layer of the Ocean
Abstract
There are contradictory opinions on the contribution of the near-surface layer of bubbles to the attenuation of low-frequency sound in the ocean. Taking into account the new experimental data on the distribution of bubbles in seawater, it is shown that the influence of the near-surface layer of bubbles on the structure of the spatial decay in sound propagation can be significant at rather typical concentrations of bubbles in the near-surface layers of the ocean. A possible explanation for the contradictions is the spatial restructuring of the field in which the main effect of the bubbles is focused on the near distance; sound attenuation at a great distance is not affected.



Primary Production and Associated Environmental Conditions in the East Siberian Sea in Autumn
Abstract
The spatial variability of primary production in the East Siberian Sea over a large-scale aquatic area was characterized for the first time by the data of cruise 69 of R/V Akademik Mstislav Keldysh in September 2017. The value of the water column primary production IPP amounted to 28 ± 13 mg C/m2 per day, which pointed to extreme oligotrophy of the treated areas during the autumn. The IPP value was limited by low incident and subsurface insolation, as well as by the concentration of nitrates. The shortage of inorganic nitrogen was partially compensated by ammonium, which also constituted the buffer preventing a phytoplankton deficiency in nitrogen.



Geophysics
The Problem of the Existence of a Strike-Slip Fault in the Arctic Ocean between Lomonosov Submarine Ridge and the Adjacent Shelf
Abstract
The junction zone between Lomonosov submarine ridge and the shelf of the East Siberian Sea was studied. The aim was to prove the absence of a strike-slip fault in the junction zone between Lomonosov Ridge and the East Siberian shelf. The problem of the existence of a fault zone in the region where the Lomonosov Ridge joins the East Siberian shelf is still currently debateable. The geological and geophysical data used to solve it are insufficient. To remove this ambiguity, seismological data obtained in neighboring areas were used. An analysis of the map of earthquake epicenters in the region showed that, if the fault zone mentioned existed, present-day intraplate seismic activity would certainly be observed within its limits. The absence of seismicity in the junction zone between Lomonosov Ridge and the adjacent shelf clearly indicates the genetic unity of these structures.



The NOx-Limiting Regime of Photochemical Ozone Generation in a Weakly Polluted Convective Boundary Layer: Observations at the ZOTTO Tall Tower Observatory in Central Siberia, 2007–2015
Abstract
Estimates of the photochemical ozone generation rate, PQ, and the ozone production efficiency (OPE) per molecule of NOx (=NO + NO2), ∆P, are obtained for the region of Central Siberia based on near surface observations of the concentrations of ozone (O3) and nitrogen oxides (NO and NO2) at ZOTTO (Zotino Tall Tower Observatory) in 2007–2015. The experimental data are approximated well by the power dependences PQ ∝ [NOx]–n + 1, ΔP ∝ [NOx]–n, n = 0.82 ± 0.06 (the determination coefficient R2 = 0.66), which correspond to the NOx-limiting regime of ozone generation in a weakly polluted air mass. The average value for the summer months ΔP ~ 30.0–43.7 [mol.O3/mol.NOx] agrees with the OPE value of 39.8 [mol.O3/mol.NOx] obtained from the numerical experiments using the GEOS-chem global transport-chemical model. The observation data indicate the significant role of anthropogenic emissions of NOx in the regional ozone balance and the necessity of taking this factor into account in predicting ecological risks in the Siberian regions that are traditionally regarded as ecologically pure.


