Enviar artigo por via de e-mail Monomers with a High Refraction Index Based on Acryloyl Derivatives of Spirocyclic Piperidin-4-One Thioacetals
- Autores: Basistyi V.S.1,2, Bukhtoyarova A.D.1, Vasil’ev E.V.1, Shelkovnikov V.V.1
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Afiliações:
- Vorozhtsov Institute of Organic Chemistry, Novosibirsk, Siberian Branch
- Novosibirsk State University
- Edição: Volume 125, Nº 1 (2018)
- Páginas: 82-87
- Seção: Optical Materials
- URL: https://ogarev-online.ru/0030-400X/article/view/165746
- DOI: https://doi.org/10.1134/S0030400X18070044
- ID: 165746
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Resumo
Dithioazaspiroheterocyclic derivatives are synthesized by condensing dithiols with piperidin-4-one in the presence of catalytic amounts of Lewis acids. Acrylic dithioazaspiroheterocyclic derivatives are obtained by the reaction with acryloyl chloride. The polymerization of monomers yields transparent polymer films of optical quality. The refractive indices for the synthesized monomers and polymers are in the range of n = 1.59–1.64.
Sobre autores
V. Basistyi
Vorozhtsov Institute of Organic Chemistry, Novosibirsk, Siberian Branch; Novosibirsk State University
Email: vev@nioch.nsc.ru
Rússia, Novosibirsk, 630090; Novosibirsk, 630090
A. Bukhtoyarova
Vorozhtsov Institute of Organic Chemistry, Novosibirsk, Siberian Branch
Email: vev@nioch.nsc.ru
Rússia, Novosibirsk, 630090
E. Vasil’ev
Vorozhtsov Institute of Organic Chemistry, Novosibirsk, Siberian Branch
Autor responsável pela correspondência
Email: vev@nioch.nsc.ru
Rússia, Novosibirsk, 630090
V. Shelkovnikov
Vorozhtsov Institute of Organic Chemistry, Novosibirsk, Siberian Branch
Email: vev@nioch.nsc.ru
Rússia, Novosibirsk, 630090
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