Monomers with a High Refraction Index Based on Acryloyl Derivatives of Spirocyclic Piperidin-4-One Thioacetals


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Dithioazaspiroheterocyclic derivatives are synthesized by condensing dithiols with piperidin-4-one in the presence of catalytic amounts of Lewis acids. Acrylic dithioazaspiroheterocyclic derivatives are obtained by the reaction with acryloyl chloride. The polymerization of monomers yields transparent polymer films of optical quality. The refractive indices for the synthesized monomers and polymers are in the range of n = 1.59–1.64.

作者简介

V. Basistyi

Vorozhtsov Institute of Organic Chemistry, Novosibirsk, Siberian Branch; Novosibirsk State University

Email: vev@nioch.nsc.ru
俄罗斯联邦, Novosibirsk, 630090; Novosibirsk, 630090

A. Bukhtoyarova

Vorozhtsov Institute of Organic Chemistry, Novosibirsk, Siberian Branch

Email: vev@nioch.nsc.ru
俄罗斯联邦, Novosibirsk, 630090

E. Vasil’ev

Vorozhtsov Institute of Organic Chemistry, Novosibirsk, Siberian Branch

编辑信件的主要联系方式.
Email: vev@nioch.nsc.ru
俄罗斯联邦, Novosibirsk, 630090

V. Shelkovnikov

Vorozhtsov Institute of Organic Chemistry, Novosibirsk, Siberian Branch

Email: vev@nioch.nsc.ru
俄罗斯联邦, Novosibirsk, 630090

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