Отправить статью по E-mail Monomers with a High Refraction Index Based on Acryloyl Derivatives of Spirocyclic Piperidin-4-One Thioacetals
- Авторы: Basistyi V.S.1,2, Bukhtoyarova A.D.1, Vasil’ev E.V.1, Shelkovnikov V.V.1
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Учреждения:
- Vorozhtsov Institute of Organic Chemistry, Novosibirsk, Siberian Branch
- Novosibirsk State University
- Выпуск: Том 125, № 1 (2018)
- Страницы: 82-87
- Раздел: Optical Materials
- URL: https://ogarev-online.ru/0030-400X/article/view/165746
- DOI: https://doi.org/10.1134/S0030400X18070044
- ID: 165746
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Аннотация
Dithioazaspiroheterocyclic derivatives are synthesized by condensing dithiols with piperidin-4-one in the presence of catalytic amounts of Lewis acids. Acrylic dithioazaspiroheterocyclic derivatives are obtained by the reaction with acryloyl chloride. The polymerization of monomers yields transparent polymer films of optical quality. The refractive indices for the synthesized monomers and polymers are in the range of n = 1.59–1.64.
Об авторах
V. Basistyi
Vorozhtsov Institute of Organic Chemistry, Novosibirsk, Siberian Branch; Novosibirsk State University
Email: vev@nioch.nsc.ru
Россия, Novosibirsk, 630090; Novosibirsk, 630090
A. Bukhtoyarova
Vorozhtsov Institute of Organic Chemistry, Novosibirsk, Siberian Branch
Email: vev@nioch.nsc.ru
Россия, Novosibirsk, 630090
E. Vasil’ev
Vorozhtsov Institute of Organic Chemistry, Novosibirsk, Siberian Branch
Автор, ответственный за переписку.
Email: vev@nioch.nsc.ru
Россия, Novosibirsk, 630090
V. Shelkovnikov
Vorozhtsov Institute of Organic Chemistry, Novosibirsk, Siberian Branch
Email: vev@nioch.nsc.ru
Россия, Novosibirsk, 630090
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