Email this article Enthalpy of formation of the trinitromethyl group
- Authors: Miroshnichenko E.A.1, Kon’kova Т.S.1, Shastin A.V.2, Vorob’ev A.B.1, Inozemtsev J.O.1, Inozemtsev A.V.1, Matyushin Y.N.1, Korsunskiy B.L.1,2
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Affiliations:
- N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
- Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences
- Issue: Vol 16, No 3 (2023)
- Pages: 124-130
- Section: Articles
- URL: https://ogarev-online.ru/2305-9117/article/view/290014
- DOI: https://doi.org/10.30826/CE23160312
- EDN: https://elibrary.ru/RWYFCC
- ID: 290014
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Abstract
The enthalpies of combustion and enthalpies of formation of three trinitromethyl derivatives of 1,3,5-triazine were determined by the calorimetric method. The data obtained can be used for calculating the energy capabilities of related compounds by the method of replacing functional groups. The thermochemical characteristics of trinitromethyl groups from 1,3,5-triazine derivatives are compared with the corresponding properties of these groups in azoles and nitroalkanes.
About the authors
Eugeny A. Miroshnichenko
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Author for correspondence.
Email: eamir02@mail.ru
Doctor of Science in chemistry, chief research scientist
Russian Federation, MoscowТatiana S. Kon’kova
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: tas-kon@mail.ru
Doctor of Science in chemistry, chief research scientist
Russian Federation, MoscowAleksey V. Shastin
Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences
Email: shastin@icp.ac.ru
Doctor of Science in chemistry, leading research scientist
Russian Federation, Chernogolovka, Moscow RegionAlexey B. Vorob’ev
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: vectr1@yandex.ru
Candidate of Science in technology, senior research scientist
Russian Federation, MoscowJaroslav O. Inozemtsev
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: vectr1@yandex.ru
senior research scientist
Russian Federation, MoscowAlexey V. Inozemtsev
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: vectr1@yandex.ru
research scientist
Russian Federation, MoscowYuriy N. Matyushin
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: ynm07@mail.ru
Doctor of Science in technology, head of laboratory
Russian Federation, MoscowBoris L. Korsunskiy
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences; Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences
Email: vectr1@yandex.ru
Doctor of Science in chemistry, chief research scientist
Moscow; Chernogolovka, Moscow RegionReferences
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