Enthalpy of formation of the trinitromethyl group

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

The enthalpies of combustion and enthalpies of formation of three trinitromethyl derivatives of 1,3,5-triazine were determined by the calorimetric method. The data obtained can be used for calculating the energy capabilities of related compounds by the method of replacing functional groups. The thermochemical characteristics of trinitromethyl groups from 1,3,5-triazine derivatives are compared with the corresponding properties of these groups in azoles and nitroalkanes.

Авторлар туралы

Eugeny Miroshnichenko

N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: eamir02@mail.ru

Doctor of Science in chemistry, chief research scientist

Ресей, Moscow

Тatiana Kon’kova

N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Email: tas-kon@mail.ru

Doctor of Science in chemistry, chief research scientist

Ресей, Moscow

Aleksey Shastin

Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences

Email: shastin@icp.ac.ru

Doctor of Science in chemistry, leading research scientist

Ресей, Chernogolovka, Moscow Region

Alexey Vorob’ev

N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Email: vectr1@yandex.ru

Candidate of Science in technology, senior research scientist

Ресей, Moscow

Jaroslav Inozemtsev

N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Email: vectr1@yandex.ru

senior research scientist

Ресей, Moscow

Alexey Inozemtsev

N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Email: vectr1@yandex.ru

research scientist

Ресей, Moscow

Yuriy Matyushin

N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Email: ynm07@mail.ru

Doctor of Science in technology, head of laboratory

Ресей, Moscow

Boris Korsunskiy

N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences; Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences

Email: vectr1@yandex.ru

Doctor of Science in chemistry, chief research scientist

Moscow; Chernogolovka, Moscow Region

Әдебиет тізімі

  1. Shastin, A. V., T. I. Godovikova, and B. L. Korsunskiy. 2003. Nitro derivatives of 1,3,5-triazine: Synthesis and properties. Russ. Chem. Rev. 72(3):279–287. doi: 10.1070/RC2003v072n03ABEH000803.
  2. Zyuzin, I. N., I. Yu. Gudkova, and D. B. Lempert. 2020. The energy capabilities of new derivatives of 1,2,4- and 1,3,4-oxadiazoles as components of solid composite propellants. Russ. J. Phys. Chem. B 14(2):302–313. doi: 10.1134/S1990793120020062.
  3. Stepanov, R. S., L. A. Kruglyakova, and A. M. Astakhov. 2007. Effect of the structure of cyclic -nitramines on the rate and mechanism of their thermolysis. Russ. J. Gen. Chem. 77(11):1293–1299. doi: 10.1134/ S1070363207070237.
  4. Shastin, A. V., T. I. Godovikova, and B. L. Korsunskiy. 2011. A new method for the synthesis of 2,4-diazido-6-trinitromethyl-1,3,5- triazine. Russ. Chem. B. 60(6):1220–1222. doi: 10.1007/s11172-011-0191-y.
  5. Inozemtsev, Ya. O., A. B. Vorobyev, A. V. Inozemtsev, and Yu. N. Matyushin. 2014. Kalorimetriya energoemkikh soedineniy [Calorimetry of energetic materials]. Goren. Vzryv (Mosk.) — Combustion and Explosion 7:260–270.
  6. Kon’kova, T. S., Yu. N. Matyushin, E. A. Miroshnichenko, and A. B. Vorob’ev . 2009. Thermochemical properties of dinitramidic acid salts. Russ. Chem. B 58(10):2020–2027. doi: 10.1007/s11172-009-0276-z.
  7. Skuratov, S. M., V. P. Kolesov, and A. F. Vorob’ev. 1966. Termokhimiya [Thermochemistry]. Moscow: Moscow University. Part II. 302 p.
  8. Miroshnichenko, E. A., V. P. Lebedev, and Yu. N. Matyushin. 2002. Energy properties of adamantane derivatives. Dokl. Phys. Chem. 382(4-6):40–42. doi: 10.1023/ A:1014499229527.
  9. Huynh, M.-H. V., M. A. Hiskey, E. L. Hartline, D. P. Montoya, and R. Gilardi. 2004. Polyazido high-nitrogen compounds: Hydrazo-and azo-1,3,5-triazine. Angew. Chem. Int. Edit. 43(37):4924–4928. doi: 10.1002/ anie.200460366.
  10. Shastin, A. V., T. I. Godovikova, S. P. Golova, L. I. Khmel’nitskii, and B. L. Korsunskii. 1995. Nucleophilic substitution reactions of 2,4,6-tris(trinitromethyl)-1,3,5-triazine. 1. Interaction of 2,4,6-tris(trinitromethyl)-1,3,5-triazine with alcohols, diols, ammonia, and secondary amines. Chem. Heterocyc. Compd. 31:596–600. doi: 10.1007/BF01166337.
  11. Shastin, A. V., T. I. Godovikova, S. P. Golova, L. I. Khmel’nitskii, and B. L. Korsunskii. 1995. Nucleophilic substitution reactions of 2,4,6-tris(trinitromethyl)-1,3,5-triazine. 2. Interaction of 2,4,6-tris(trinitromethyl)-1,3,5-triazine with primary amines and hexamethyldisilazane. Chem. Heterocyc. Compd. 31:601–609. doi: 10.1007/BF01166338.
  12. Shastin, A. V., and D. B. Lempert. 2016. Enthalpies of formation of trinitromethyl-substituted aromatic and heteroaromatic compounds and their efficiency as oxidizers in energetic compositions. Russ. J. Phys. Chem. B 10(4):632–638. doi: 10.1134/S1990793116040266.

Қосымша файлдар

Қосымша файлдар
Әрекет
1. JATS XML

Согласие на обработку персональных данных

 

Используя сайт https://journals.rcsi.science, я (далее – «Пользователь» или «Субъект персональных данных») даю согласие на обработку персональных данных на этом сайте (текст Согласия) и на обработку персональных данных с помощью сервиса «Яндекс.Метрика» (текст Согласия).