Formation and Properties of Electron- and Ion-Conducting Layers of N-Substituted PVC Derivatives Grafted onto Active Carbon


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Resumo

A systematization is presented of studies of carbon sorbent functionalization based on chemical modification of the active carbon surface by covalent grafting of macromolecular N-substituted cyclic amines. Thus, porous electron-conducting and luminescent layers grafted onto supports are obtained. The layers can sorb organic compounds. After sorption of acids, hydroxides, and metal salts, the layers become electron- and ion-conducting. Here, hydrogen is formed as in cathodically polarized electrochemical bridges and oxygen is formed as in anodically polarized electrochemical bridges. Principles of layer formation are considered on the surface of the material of cellulose fibers and asbestos cloth, as well as nickel filaments. Specific features of such functionalized sorbents are shown.

Sobre autores

I. Bardyshev

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Autor responsável pela correspondência
Email: bardyshev@phyche.ac.ru
Rússia, Moscow, 119071

I. Polyakova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
Rússia, Moscow, 119071

A. Gorbunov

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
Rússia, Moscow, 119071

V. Titova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
Rússia, Moscow, 119071

A. Yavich

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
Rússia, Moscow, 119071

A. Tsivadze

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
Rússia, Moscow, 119071

A. Fridman

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
Rússia, Moscow, 119071

A. Averin

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
Rússia, Moscow, 119071

M. Shabanov

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
Rússia, Moscow, 119071

E. Morozova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
Rússia, Moscow, 119071

G. Petukhova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
Rússia, Moscow, 119071

A. Novikov

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
Rússia, Moscow, 119071

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