Formation and Properties of Electron- and Ion-Conducting Layers of N-Substituted PVC Derivatives Grafted onto Active Carbon
- Авторы: Bardyshev I.I.1, Polyakova I.Y.1, Gorbunov A.M.1, Titova V.N.1, Yavich A.A.1, Tsivadze A.Y.1, Fridman A.Y.1, Averin A.A.1, Shabanov M.P.1, Morozova E.M.1, Petukhova G.A.1, Novikov A.K.1
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Учреждения:
- Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- Выпуск: Том 55, № 6 (2019)
- Страницы: 1071-1079
- Раздел: Physicochemical Processes at the Interfaces
- URL: https://ogarev-online.ru/2070-2051/article/view/205563
- DOI: https://doi.org/10.1134/S2070205119050265
- ID: 205563
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Аннотация
A systematization is presented of studies of carbon sorbent functionalization based on chemical modification of the active carbon surface by covalent grafting of macromolecular N-substituted cyclic amines. Thus, porous electron-conducting and luminescent layers grafted onto supports are obtained. The layers can sorb organic compounds. After sorption of acids, hydroxides, and metal salts, the layers become electron- and ion-conducting. Here, hydrogen is formed as in cathodically polarized electrochemical bridges and oxygen is formed as in anodically polarized electrochemical bridges. Principles of layer formation are considered on the surface of the material of cellulose fibers and asbestos cloth, as well as nickel filaments. Specific features of such functionalized sorbents are shown.
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Об авторах
I. Bardyshev
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
I. Polyakova
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
A. Gorbunov
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
V. Titova
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
A. Yavich
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
A. Fridman
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
A. Averin
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
M. Shabanov
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
E. Morozova
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
G. Petukhova
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
A. Novikov
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
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