Vol 23, No 1 (2021)

TECHNOLOGY

Technology of obtaining composite conglomerate powders for plasma spraying of high-temperature protective coatings

Guzanov B.N., Pugacheva N.B., Slukin E.Y., Bykova T.M.

Abstract

Introduction. For parts of gas turbines operating under conditions of corrosion-erosion and intense wear, the most acceptable are compositions containing Ni, Co, Cr, Al, B, Y both in pure form and in the composition of compounds applied on the contact surface during thermal spraying. Modern integrated complexes obtained by combining dissimilar substances in the form of a single composition are promising. Such powders are obtained either by cladding or by conglomeration of finely dispersed starting components into a larger particle. The problem of developing and manufacturing plants for conglomeration of powders is urgent and practically important, since it makes it possible to obtain material for thermal spraying of coatings for high-temperature purposes. The aim of the work is to develop a technological scheme for obtaining powders of the required chemical composition with a given particle shape and size, intended for spraying high-temperature protective coatings. Materials and research methods. A technology is developed for the production of integrated powders for spraying coatings using the method of spray drying and subsequent sintering in vacuum or in an argon-hydrogen atmosphere, which avoids the loss of feedstock due to the return of fine and coarse fractions. A technology for preparing materials for spray drying and granulation is proposed. A gravity type aerodynamic classifier is designed and manufactured, which makes it possible to select automatically the powder fraction necessary for spraying the coating, as well as return the unwanted fraction for recycling. The morphology of the granular powder is determined using a TESCAN scanning electron microscope. The chemical composition of the resulting integrated complexes is determined by X-ray microanalysis on an OXFORD attachment. Results and discussion. The technological conditions for obtaining powders of a given size (40…100 µm) are established. It is shown that the shape of the conglomerate particles after spray drying is close to spherical. On the basis of a multifactor experiment, the optimization of the technological process for obtaining powders Ni-17Cr-10Al-1Y and Ni-22Cr-16Al-1Y with sizes up to 100 µm is performed. It is shown that when conglomerating powders with increased aluminum content (Ni-22Cr-16Al-1Y), it is necessary to take into account the exothermic reaction of nickel aluminide formation and dilute the mixture of initial components before sintering with the finished sintered powder. The resulting integrated complexes are characterized by high heat resistance; therefore they are designed and successfully used for plasma spraying of protective coatings for high-temperature purposes. Conclusions. A technology is developed for obtaining composite conglomerated powders Ni-17C-10Al-1Y and Ni-22Cr-16Al-1Y with particle sizes up to 100 µm and a shape close to spherical. A distinctive feature of this technology is that it avoids the loss of feedstock by returning fine and coarse fractions.
Obrabotka Metallov / Metal Working and Material Science. 2021;23(1):6-20
pages 6-20 views

Investigation of the machinability by milling of the laser sintered Inconel 625/NiTi-TiB2 composite

Arlyapov A.Y., Volkov S.Y., Promakhov V.V., Zhukov A.S.

Abstract

Introduction. The processing capability of milling a metal-matrix composite based on Inconel 625 with the addition of NiTi-TiB2, obtained by laser sintering, is investigated. The composite is intended for turbine blades manufacture and has strength characteristics close to Inconel 625, however, due to the addition of TiB2, its’; heat- and wear resistance is higher. This material is new; its machinability has not been studied yet. The aim of the work is to determine the technological capabilities of milling with end mills of this composite. Investigations. The new composite is milled with end mills, and recommendations on the selection of cutting speed, milling depth and width are obtained. Experimental Methods. Measuring end mill wear and cutting force. Wear is assessed by the flank chamfer using a microscope, and cutting forces are measured with a Kistler 9257B dynamometer. Milling is carried out at three speeds: 25, 35 and 50 m/min. To determine the optimal parameters of the depth and width of milling, the following ratios are used: 1: 1, 1: 4; 1:16, while the volume of chips removed per unit of time remained constant for all ratios. Results and Discussion. The back surface of the cutter teeth wears out more intensively. After reaching the wear chamfer along the flank surface of a value equal to 0.11 - 0.15 mm, there is a sharp increase in forces and brittle destruction of the tooth. Milling at a speed of 25 m/min guaranteed 28 minutes of stable operation, after which the amount of wear quickly approached the critical value of 0.11 mm, at a cutting speed of 50 m/min, critical wear occurred already after 14 minutes. The dependences of the cutting force on time for all selected cutting speeds, throughout the test time, have an increasing character, which indicates the effect of wear of cutters on cutting forces. It is found that the durability of cutters increases with increasing width and decreasing the depth of milling.
Obrabotka Metallov / Metal Working and Material Science. 2021;23(1):21-32
pages 21-32 views

Determination of temperature of maximum operability of replaceable cutting hard-alloy inserts based on study of electromagnetic properties change

Artamonov E.V., Tveryakov A.M., Shtin A.S.

Abstract

Introduction. Today, under the conditions of sanctions, the Russian Federation, more than ever before, needs the development of energy-saving technologies in various industries. There is no secret that when assigning cutting modes for new materials, tool companies conduct tests for the destruction of replaceable cutting inserts during cutting, the obtained numerical values are published in catalogs. The greatest impact on the life and operability of hard alloy cutting tools is exerted by the physical and mechanical properties of tool materials. Studies have shown that the physical and mechanical properties of tungsten hard alloys in the process of operation, namely in the process of cutting difficult-to-process materials under the influence of high temperatures, vary symmetrically. During the development of the laboratory plant, a literary review was carried out, which showed that at the moment non-destructive testing methods of technological facilities are widely used. Methods of non-destructive testing of technological objects allow conducting studies of the state of material, defects in the structure, internal changes, without samples destroying; this advantage was decisive during the literary review. The object of this study is replaceable cutting hard alloy inserts made of single carbide hard alloy В35 (92%WC+8%Co), tetrahedral in the state of supply. The subject of the study is the relationship between the changes of the magnetic component of the properties of a single-carbide hard alloy В35 (92%WC+8%Co) depending on the effect of high temperatures on it. This study is based on the laws of physics of the division of electrodynamics, as well as well-known non-destructive testing techniques, scientific foundations of material science. All studies are carried out in accredited laboratories of Tyumen Industrial University. The reliability of the obtained data is confirmed by the high correlation of the results of numerical values with the data obtained by the scientific predecessors. Research methodology. The paper shows the developed plant for determination of the maximum operability temperature of replaceable cutting hard-alloy inserts on the basis of study of change of electromagnetic properties. The method of research is given. Tests of the specimen are carried out during heating of replaceable cutting inserts made of tungsten hard alloy B35 (92%WC+8%Co). The heating temperature interval is selected in accordance with the temperature mode of the cutting process in the blade treatment of hard-to-process materials. Thus, heating is carried out in the range from 0 to 1000? C. The heating itself is carried out by the flame method manually. Results and discussions. Based on the results of experimental studies, tables of the results are compiled, where, with an interval of 10 °C, the corresponding values of the magnetic field of eddy currents induced in replaceable cutting inserts made of tungsten hard alloy B35 (92 %WC+8 %Co) are indicated. The results of the investigation are obtained to determine the maximum operability temperature of replaceable cutting hard alloy inserts based on the study of the change in electromagnetic properties for the hard alloy B35 (92%WC+8%Co) amounted to 460…730 °C, which corresponds to a cutting speed of 18 m/min during the treatment of the alloy EI867-VD (57 %Ni9 %Mo10 %Cr6 %W4.2 %Al4 %Co). On the basis of persistent tests in factory conditions, it is proved that the developed technique allows determining temperature intervals of maximum operability based on the study of changes in electromagnetic properties (magnetic field of eddy currents arising in replaceable cutting inserts) of hard alloys. These intervals make it possible to assign the most appropriate operating conditions for the cutting tool based on a scientifically sound technique that allows using the maximum tool resource.
Obrabotka Metallov / Metal Working and Material Science. 2021;23(1):33-44
pages 33-44 views

Evaluation of the level of hardening of aluminum alloy chips intended for subsequent pressure treatment

Loginov Y.N., Zagirov N.N., Ivanov E.V.

Abstract

Introduction. It is noted that the chip is an undesirable type of metal scrap, because it has a developed surface, which creates conditions for more intense interaction with the surrounding atmosphere. This creates conditions for oxidation and gas saturation, especially at elevated temperatures typical of remelting processes. Therefore, the process of chip utilizing is considered, bypassing the remelting stage. The aim of the work is to establish the level of work hardening of chips during the processing of aluminum alloys and to predict its effect on the subsequent processing process. Research methods: to assess the deformed state, the finite element method was applied, implemented in the RAPID-2D software package. The sequence of actions included the creation of the initial shape of the deformation region and the configuration of the tool. The mutual displacement of the tool and the deformable material is specified using the corresponding boundary conditions. The deformable medium is a viscous-plastic material with power-law hardening, the physical and mechanical properties correspond to an aluminum-magnesium alloy. Results and discussion: the solution obtained shows that the degree of shear deformation in the chips can reach a value of more than 2. In this case, a higher level of deformation is localized on the side of the convex part of the chip. The comparison of the solution with those obtained earlier by other authors is carried out and its similarity is shown. In the considered solution, the difference in the degree of work-hardening of the chips along its thickness is 36 %. A variant of the sequence of processing the workpiece first by cold deformation, and then by cutting is considered. The field of application of the results of the work is the development of methods for the processing of technogenic formations. Conclusions. During the cutting process, the plastic deformation of the chips reaches significant values. In this paper, the difference in the degree of shear deformation in the chip thickness is established, depending on the proximity of the cut layer to the surface of the cutting tool. It is proposed to take this difference into account at the subsequent stages of chip processing. The presence of the marked inhomogeneity of mechanical properties leads to consequences in the form of an inhomogeneous distribution of the temperature of the beginning of recrystallization during subsequent operations of heat treatment or hot deformation treatment. The principle of additivity of the degree of deformation obtained by the metal at the stage of plastic shaping of the workpiece and the shaping of the chip itself is introduced.
Obrabotka Metallov / Metal Working and Material Science. 2021;23(1):45-55
pages 45-55 views

EQUIPMENT. INSTRUMENTS

Determination of optimal coordinates for switching processing cycles on metal-cutting machines

Zakovorotny V.L., Gvindjiliya V.E.

Abstract

Introduction. One of the ways to improve the efficiency of processing on machines is to coordinate the CNC program with the changing properties of the dynamic cutting system. If this takes into account the tool wear and the associated with it changes in the parameters of the dynamic cutting system, then the cutting speed to ensure the minimum wear rate is reduced along the cutting path. The corresponding feed rate is reduced even faster, since it is necessary to ensure a constant deformation displacement of the tool relative to the workpiece. The evolution of the properties of the cutting process (for matching with which the trajectories of the operating elements of the machine are corrected) depends on the power of irreversible transformations of the energy supplied to cutting. This reduces the processing efficiency. Therefore, a new for the considered subject area problem of determining the coordinates of the tool movement relative to the workpiece is formulated, starting from which further processing is economically inexpedient. In this case, it is necessary, after processing the next part, to ensure the replacement of the tool and carry out its changeover. Subject. A metal-cutting machine of a turning group, the trajectories of the executive elements of which are controlled, for example, by a CNC system. The purpose of the work. Mathematical simulation and methods for determining the coordinates at which it is necessary to replace the tool. Method and methodology. The necessary conditions for the optimality of determining these coordinates are proved. Mathematical tools are provided that allow calculating the coordinates at which the given manufacturing costs take the minimum value according to the given trajectories. The probabilistic characteristics of evolutionary trajectories are taken into account. Results and discussions. The analysis of the efficiency of using the technique in industry depending on the cost of the machine and tool together with its replacement and readjustment is given. The proven optimality conditions and the given mathematical tools complement the knowledge about the optimization of controlled machining processes on machines. Conclusions. The results of the study show new options for the organization of tool replacement, aimed at improving the efficiency of processing by software methods using a CNC system.
Obrabotka Metallov / Metal Working and Material Science. 2021;23(1):56-67
pages 56-67 views

MATERIAL SCIENCE

Effect of mechanical activation of WC-based powder on the properties of sintered alloys

Abdulmenova E.V., Kulkov S.N.

Abstract

Introduction. For the manufacture of wearproof tools and machine elements, the method of powder metallurgy is widely used. The preliminary high-intensity mechanical activation of the powder is used to improve the structure and properties of the alloy obtained by the method of powder metallurgy. The mechanical activation can result in formation of nanostructures with subsequent amorphization of the material, can bring phase transformations, it can certainly affect the properties of the material. However, mechanical treatment does not always lead to a positive result. Therefore, the study of the effect of mechanical activation of WC-based powder on the properties of sintered alloys is important. Purpose of the work: to study the effect of high-intensity mechanical activation of WC-based powder on the structure and properties of sintered samples. The work investigates alloys obtained by the method of powder metallurgy, using mechanically activated powders for 10 to 300 seconds in a planetary ball mill. Materials and methods. The alloys are obtained by cold one-sided pressing followed by sintering at a temperature of 1400 °C in a vacuum furnace. Particle morphology of powder and structure of alloys is analyzed by scanning electron microscopy method. The metallographic analysis of the alloys is carried out by optical microscopy. Phase analysis and the parameters of the crystal structure are performed by X-ray diffraction. The hardness of the sintered samples is measured by hardness tester. Results and its discussion. It is shown that after sintering of powders alloys with WC and Co phases are formed. The lattice parameter of the WC-phase correlates well with values in literature. A second carbide phase, Co3W3C, is formed in the samples upon mechanical activation for more than 100 sec. The minimum porosity of sintered sample is 7.8 ± 1 % that corresponds of sample with preliminary mechanical treatment for 30 seconds. It is shown that the hardness depends on grain size, porosity and second carbide content. Thus, mechanical activation can be effective for increasing the physical and mechanical properties and inhibiting grain growth, but in this case, it is necessary to carry out mechanical processing in the mechanical treatment time range 60-100 sec.
Obrabotka Metallov / Metal Working and Material Science. 2021;23(1):68-78
pages 68-78 views

Invariant stress state parameters for forging upsetting of magnesium in the shell

Loginov Y.N., Zamaraeva Y.V.

Abstract

Introduction. For pressure treatment of low-plastic metals, it is necessary to develop special techniques for increasing plasticity. In the cold state, an increase in plastic properties is possible due to an increase in the level of compressive stresses during deformation. In the processes of forging precipitation, this is achieved by using shells or clips of various types. At the same time, the configuration of the precipitation tool also matters. To create additional compressive stresses and increase the ductility of the metal, the working surface of the tool can be configured differently than with a normal free draft, where it is obviously larger than the contact surface area of the workpiece, so that metal broadening can occur. The stress state has a great influence on the plasticity of the processed material. This state is described by methods of tensor representation, but to assess the situation, it is customary to use invariants of tensors in one form or another, which eliminates the influence of coordinates on the results of the analysis. In the sections of deformable body mechanics dealing with the influence of the stress state on plasticity, the first, but sometimes other invariants of the stress tensor are used, the invariants themselves are transformed into the stress state indicator and the lode coefficient. The aim of the work: mathematical evaluation of invariant parameters of the stress state of the magnesium precipitation process at room temperature, according to the results of which it is possible to obtain a positive result in real experiments. Research methods: finite element simulation using the DEFORM software module. Results and discussion. The theoretical justification of increasing the plasticity of the magnesium billet in the process of precipitation in the cage without its compression is carried out. An increase in the stress state index modulo 2...5 times is revealed, which contributes to an increase in the plasticity of the metal. At the same time, a zone with a lode coefficient close to zero is identified. It is adjacent to the middle of the height of the workpiece at the point of contact with the cage and can be a dangerous cross-section from the position of crack formation.
Obrabotka Metallov / Metal Working and Material Science. 2021;23(1):79-88
pages 79-88 views

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