2D coordination polymers of Ag I —M II  (M II  = Ni, Cu) with anions of substituted malonic acids

E. N. Zorina-Tikhonova; N. V. Gogoleva; E. V. Aleksandrov; G. G. Aleksandrov; M. A. Kiskin; A. A. Sidorov; I. L. Eremenko

doi:10.1007/s11172-016-1370-7

2D coordination polymers of Ag^I—M^II (M^II = Ni, Cu) with anions of substituted malonic acids

作者: Zorina-Tikhonova E.N.¹, Gogoleva N.V.¹, Aleksandrov E.V.²^,3, Aleksandrov G.G.¹, Kiskin M.A.¹, Sidorov A.A.¹, Eremenko I.L.¹
隶属关系:
1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
2. Samara Center for Theoretical Materials Science, Samara State University.
3. S. P. Korolev Samara State Aerospace University (National Research University)
期: 卷 65, 编号 3 (2016)
页面: 759-766
栏目: Full Articles
URL: https://ogarev-online.ru/1066-5285/article/view/237582
DOI: https://doi.org/10.1007/s11172-016-1370-7
ID: 237582

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Heterometallic malonate complexes [Ag₂Ni(H₂O)₂(R₂mal)₂]_n (R₂mal^2– is the dimethylmalonate dianion (Me₂mal^2–) (1) or the cyclobutane-1,1-dicarboxylate dianion (Cbdc^2–) (2)) and [Ag₂Cu(H₂O)(Me₂mal)₂]_n (3) were synthesized. The bis-chelate fragment {M(R₂mal)₂} (M = Ni, Cu) composed of two dianions of an acid and a 3d metal atom is the structure-forming unit of these complexes. The mononuclear fragments are linked by silver(I) atoms, which are involved in argentophilic interactions, to form 2D coordination polymers.

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2D coordination polymers of Ag^I—M^II (M^II = Ni, Cu) with anions of substituted malonic acids

全文:

详细

作者简介

E. Zorina-Tikhonova

N. Gogoleva

E. Aleksandrov

G. Aleksandrov

M. Kiskin

A. Sidorov

I. Eremenko

补充文件

2D coordination polymers of AgI—MII (MII = Ni, Cu) with anions of substituted malonic acids

全文:

详细

作者简介

E. Zorina-Tikhonova

N. Gogoleva

E. Aleksandrov

G. Aleksandrov

M. Kiskin

A. Sidorov

I. Eremenko

补充文件

2D coordination polymers of Ag^I—M^II (M^II = Ni, Cu) with anions of substituted malonic acids