Email this article 2D coordination polymers of AgI—MII (MII = Ni, Cu) with anions of substituted malonic acids
- Authors: Zorina-Tikhonova E.N.1, Gogoleva N.V.1, Aleksandrov E.V.2,3, Aleksandrov G.G.1, Kiskin M.A.1, Sidorov A.A.1, Eremenko I.L.1
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Affiliations:
- N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Samara Center for Theoretical Materials Science, Samara State University.
- S. P. Korolev Samara State Aerospace University (National Research University)
- Issue: Vol 65, No 3 (2016)
- Pages: 759-766
- Section: Full Articles
- URL: https://ogarev-online.ru/1066-5285/article/view/237582
- DOI: https://doi.org/10.1007/s11172-016-1370-7
- ID: 237582
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Abstract
Heterometallic malonate complexes [Ag2Ni(H2O)2(R2mal)2]n (R2mal2– is the dimethylmalonate dianion (Me2mal2–) (1) or the cyclobutane-1,1-dicarboxylate dianion (Cbdc2–) (2)) and [Ag2Cu(H2O)(Me2mal)2]n (3) were synthesized. The bis-chelate fragment {M(R2mal)2} (M = Ni, Cu) composed of two dianions of an acid and a 3d metal atom is the structure-forming unit of these complexes. The mononuclear fragments are linked by silver(I) atoms, which are involved in argentophilic interactions, to form 2D coordination polymers.
About the authors
E. N. Zorina-Tikhonova
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: kamphor@mail.ru
Russian Federation, 31 Leninsky prosp., Moscow, 119991
N. V. Gogoleva
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: kamphor@mail.ru
Russian Federation, 31 Leninsky prosp., Moscow, 119991
E. V. Aleksandrov
Samara Center for Theoretical Materials Science, Samara State University.; S. P. Korolev Samara State Aerospace University (National Research University)
Email: kamphor@mail.ru
Russian Federation, 1 ul. Akademika Pavlova, Samara, 443011; 34 Moskovskoye shosse, Samara, 443086
G. G. Aleksandrov
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: kamphor@mail.ru
Russian Federation, 31 Leninsky prosp., Moscow, 119991
M. A. Kiskin
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: kamphor@mail.ru
Russian Federation, 31 Leninsky prosp., Moscow, 119991
A. A. Sidorov
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: kamphor@mail.ru
Russian Federation, 31 Leninsky prosp., Moscow, 119991
I. L. Eremenko
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: kamphor@mail.ru
Russian Federation, 31 Leninsky prosp., Moscow, 119991
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