2D coordination polymers of AgI—MII (MII = Ni, Cu) with anions of substituted malonic acids


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Аннотация

Heterometallic malonate complexes [Ag2Ni(H2O)2(R2mal)2]n (R2mal2– is the dimethylmalonate dianion (Me2mal2–) (1) or the cyclobutane-1,1-dicarboxylate dianion (Cbdc2–) (2)) and [Ag2Cu(H2O)(Me2mal)2]n (3) were synthesized. The bis-chelate fragment {M(R2mal)2} (M = Ni, Cu) composed of two dianions of an acid and a 3d metal atom is the structure-forming unit of these complexes. The mononuclear fragments are linked by silver(I) atoms, which are involved in argentophilic interactions, to form 2D coordination polymers.

Авторлар туралы

E. Zorina-Tikhonova

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: kamphor@mail.ru
Ресей, 31 Leninsky prosp., Moscow, 119991

N. Gogoleva

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: kamphor@mail.ru
Ресей, 31 Leninsky prosp., Moscow, 119991

E. Aleksandrov

Samara Center for Theoretical Materials Science, Samara State University.; S. P. Korolev Samara State Aerospace University (National Research University)

Email: kamphor@mail.ru
Ресей, 1 ul. Akademika Pavlova, Samara, 443011; 34 Moskovskoye shosse, Samara, 443086

G. Aleksandrov

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: kamphor@mail.ru
Ресей, 31 Leninsky prosp., Moscow, 119991

M. Kiskin

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: kamphor@mail.ru
Ресей, 31 Leninsky prosp., Moscow, 119991

A. Sidorov

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: kamphor@mail.ru
Ресей, 31 Leninsky prosp., Moscow, 119991

I. Eremenko

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: kamphor@mail.ru
Ресей, 31 Leninsky prosp., Moscow, 119991

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