Modification of polymer surfaces based on polyurethanes with photochromic compounds


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Аннотация

The possibility of covalent fixing of hydroxyl-containing photochromic compounds on the surface of polyurethane films containing excess isocyanate groups was studied. By comparing the spectral-kinetic characteristics of polyurethane films treated with solutions and films with chromene or spirooxazine derivatives introduced into the bulk polymer, it was concluded that in the first case the polymer swells and the photochromic compound becomes distributed predominantly in the bulk polymer rather than on the surface.

Авторлар туралы

V. Grachev

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: grachov@icp.ac.ru
Ресей, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

A. Dzhalmukhanova

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: grachov@icp.ac.ru
Ресей, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

E. Yurieva

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: grachov@icp.ac.ru
Ресей, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

S. Kurochkin

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: grachov@icp.ac.ru
Ресей, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

V. Barachevsky

Center of Photochemistry, Russian Academy of Sciences

Email: grachov@icp.ac.ru
Ресей, 7a ul. Novatorov, Moscow, 119421

A. Gorelik

Center of Photochemistry, Russian Academy of Sciences

Email: grachov@icp.ac.ru
Ресей, 7a ul. Novatorov, Moscow, 119421

N. Zaichenko

Institute of Chemical Physics, Russian Academy of Sciences

Email: grachov@icp.ac.ru
Ресей, 4 ul. Kosygina, Moscow, 119991

S. Aldoshin

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: grachov@icp.ac.ru
Ресей, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

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