Modification of polymer surfaces based on polyurethanes with photochromic compounds


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The possibility of covalent fixing of hydroxyl-containing photochromic compounds on the surface of polyurethane films containing excess isocyanate groups was studied. By comparing the spectral-kinetic characteristics of polyurethane films treated with solutions and films with chromene or spirooxazine derivatives introduced into the bulk polymer, it was concluded that in the first case the polymer swells and the photochromic compound becomes distributed predominantly in the bulk polymer rather than on the surface.

作者简介

V. Grachev

Institute of Problems of Chemical Physics, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: grachov@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

A. Dzhalmukhanova

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: grachov@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

E. Yurieva

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: grachov@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

S. Kurochkin

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: grachov@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

V. Barachevsky

Center of Photochemistry, Russian Academy of Sciences

Email: grachov@icp.ac.ru
俄罗斯联邦, 7a ul. Novatorov, Moscow, 119421

A. Gorelik

Center of Photochemistry, Russian Academy of Sciences

Email: grachov@icp.ac.ru
俄罗斯联邦, 7a ul. Novatorov, Moscow, 119421

N. Zaichenko

Institute of Chemical Physics, Russian Academy of Sciences

Email: grachov@icp.ac.ru
俄罗斯联邦, 4 ul. Kosygina, Moscow, 119991

S. Aldoshin

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: grachov@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

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