Email this article Reduction of (1,3-diformylindenyl)cyclopentadienylruthenium derivatives
- Authors: Kuklin S.A.1, Sheloumov A.M.1, Kamyshova A.A.1, Koridze A.A.2, Safronov S.V.1
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Affiliations:
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Institute of Organometallic Chemistry, I. Javakhishvili Tbilisi State University
- Issue: Vol 67, No 1 (2018)
- Pages: 33-35
- Section: Article
- URL: https://ogarev-online.ru/1066-5285/article/view/241895
- DOI: https://doi.org/10.1007/s11172-018-2033-7
- ID: 241895
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Abstract
The reduction of the (1,3-diformylindenyl)cyclopentadienylruthenium derivatives {η5-1,3-(CHO)2C9H5}RuCp (Cp = C5H5), {η5-1,3-(CHO)2C9H5}RuCp* (Cp* = C5Me5), and {η5-1,3-(CHO)2C9H5}RuCpF (CpF = C5Me4CF3) with NaBH4 or LiAlH4 under mild conditions affords the [1,3-bis(hydroxymethyl)indenyl]cyclopentadienylruthenium complexes {η5-1,3-(CH2OH)2C9H5}RuCp, {η5-1,3-(CH2OH)2C9H5}RuCp*, and {η5-1,3-(CH2OH)2C9H5}-RuCpF, respectively, in good yields.
About the authors
S. A. Kuklin
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: sergiosfr-hcc@mail.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
A. M. Sheloumov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: sergiosfr-hcc@mail.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
A. A. Kamyshova
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: sergiosfr-hcc@mail.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
A. A. Koridze
Institute of Organometallic Chemistry, I. Javakhishvili Tbilisi State University
Email: sergiosfr-hcc@mail.ru
Georgia, 3 Chavchavadze Avenue, Tbilisi, 0128
S. V. Safronov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Author for correspondence.
Email: sergiosfr-hcc@mail.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
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