Reduction of (1,3-diformylindenyl)cyclopentadienylruthenium derivatives

S. A. Kuklin; A. M. Sheloumov; A. A. Kamyshova; A. A. Koridze; S. V. Safronov

doi:10.1007/s11172-018-2033-7

Reduction of (1,3-diformylindenyl)cyclopentadienylruthenium derivatives

作者: Kuklin S.A.¹, Sheloumov A.M.¹, Kamyshova A.A.¹, Koridze A.A.², Safronov S.V.¹
隶属关系:
1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
2. Institute of Organometallic Chemistry, I. Javakhishvili Tbilisi State University
期: 卷 67, 编号 1 (2018)
页面: 33-35
栏目: Article
URL: https://ogarev-online.ru/1066-5285/article/view/241895
DOI: https://doi.org/10.1007/s11172-018-2033-7
ID: 241895

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The reduction of the (1,3-diformylindenyl)cyclopentadienylruthenium derivatives {η⁵-1,3-(CHO)₂C₉H₅}RuCp (Cp = C₅H₅), {η⁵-1,3-(CHO)₂C₉H₅}RuCp* (Cp* = C₅Me₅), and {η⁵-1,3-(CHO)₂C₉H₅}RuCpF (Cp^F = C₅Me₄CF₃) with NaBH₄ or LiAlH₄ under mild conditions affords the [1,3-bis(hydroxymethyl)indenyl]cyclopentadienylruthenium complexes {η⁵-1,3-(CH₂OH)₂C₉H₅}RuCp, {η⁵-1,3-(CH₂OH)₂C₉H₅}RuCp*, and {η⁵-1,3-(CH₂OH)₂C₉H₅}-RuCp^F, respectively, in good yields.

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ruthenium, ruthenocenes, metallocenes, sandwich complexes, reduction, cyclopentadienyl, pentamethylcyclopentadienyl, (trifluoromethyl)tetramethylcyclopentadienyl, 1,3-diformylindenyl, 1,3-bis(hydroxymethyl)indenyl, homoannular

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Reduction of (1,3-diformylindenyl)cyclopentadienylruthenium derivatives

全文:

详细

关键词

作者简介

S. Kuklin

A. Sheloumov

A. Kamyshova

A. Koridze

S. Safronov

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