Email this article Determination of the reaction acceleration effect at an elevated hydrostatic pressure
- Authors: Kornilov D.A.1, Kiselev V.D.1, Konovalov A.I.2
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Affiliations:
- A. M. Butlerov Chemical Institute, Kazan (Volga Region) Federal University
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
- Issue: Vol 66, No 3 (2017)
- Pages: 564-566
- Section: Brief Communications
- URL: https://ogarev-online.ru/1066-5285/article/view/240323
- DOI: https://doi.org/10.1007/s11172-017-1772-1
- ID: 240323
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Abstract
A method was proposed for the calculation of changes in the rate (kP/kP=0) and equilibrium constants (KP/KP=0) for chemical reactions under high hydrostatic pressure (10—20 kbar). The calculation based on the activation and reaction volume data makes it possible to select optimum conditions for slow and equilibrium chemical processes.
About the authors
D. A. Kornilov
A. M. Butlerov Chemical Institute, Kazan (Volga Region) Federal University
Email: vkiselev.ksu@gmail.com
Russian Federation, 18 ul. Kremlevskaya, Kazan, 420008
V. D. Kiselev
A. M. Butlerov Chemical Institute, Kazan (Volga Region) Federal University
Author for correspondence.
Email: vkiselev.ksu@gmail.com
Russian Federation, 18 ul. Kremlevskaya, Kazan, 420008
A. I. Konovalov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: vkiselev.ksu@gmail.com
Russian Federation, 8 ul. Arbuzova, Kazan, 420088
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