Determination of the reaction acceleration effect at an elevated hydrostatic pressure


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A method was proposed for the calculation of changes in the rate (kP/kP=0) and equilibrium constants (KP/KP=0) for chemical reactions under high hydrostatic pressure (10—20 kbar). The calculation based on the activation and reaction volume data makes it possible to select optimum conditions for slow and equilibrium chemical processes.

Sobre autores

D. Kornilov

A. M. Butlerov Chemical Institute, Kazan (Volga Region) Federal University

Email: vkiselev.ksu@gmail.com
Rússia, 18 ul. Kremlevskaya, Kazan, 420008

V. Kiselev

A. M. Butlerov Chemical Institute, Kazan (Volga Region) Federal University

Autor responsável pela correspondência
Email: vkiselev.ksu@gmail.com
Rússia, 18 ul. Kremlevskaya, Kazan, 420008

A. Konovalov

A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences

Email: vkiselev.ksu@gmail.com
Rússia, 8 ul. Arbuzova, Kazan, 420088

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