Kinetics of Pu(VI) Reduction with Diformylhydrazine in Nitric Acid
- Авторы: Dvoeglazov K.N.1, Pavlyukevich E.Y.1, Mitrikas P.V.1
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Учреждения:
- Bochvar High-Tech Research Institute of Inorganic Materials
- Выпуск: Том 60, № 6 (2018)
- Страницы: 588-594
- Раздел: Article
- URL: https://ogarev-online.ru/1066-3622/article/view/224761
- DOI: https://doi.org/10.1134/S1066362218060048
- ID: 224761
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Аннотация
The kinetics of the Pu(VI) reduction with diformylhydrazine in a nitric acid medium was studied by spectrophotometry. The reaction rate increases with an increase in the reductant concentration and temperature and decreases with an increase in the HNO3 concentration. The reaction order with respect to Pu, diformylhydrazine, and HNO3 is 1, 1.3, and–1.5, respectively. The activation energy of the reaction is 86.9 kJ mol–1.
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Об авторах
K. Dvoeglazov
Bochvar High-Tech Research Institute of Inorganic Materials
Автор, ответственный за переписку.
Email: KNDvoeglazov@bochvar.ru
Россия, ul. Rogova 5a, Moscow, 123060
E. Pavlyukevich
Bochvar High-Tech Research Institute of Inorganic Materials
Email: KNDvoeglazov@bochvar.ru
Россия, ul. Rogova 5a, Moscow, 123060
P. Mitrikas
Bochvar High-Tech Research Institute of Inorganic Materials
Email: KNDvoeglazov@bochvar.ru
Россия, ul. Rogova 5a, Moscow, 123060
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