Email this article Kinetics of Pu(VI) Reduction with Diformylhydrazine in Nitric Acid
- Authors: Dvoeglazov K.N.1, Pavlyukevich E.Y.1, Mitrikas P.V.1
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Affiliations:
- Bochvar High-Tech Research Institute of Inorganic Materials
- Issue: Vol 60, No 6 (2018)
- Pages: 588-594
- Section: Article
- URL: https://ogarev-online.ru/1066-3622/article/view/224761
- DOI: https://doi.org/10.1134/S1066362218060048
- ID: 224761
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Abstract
The kinetics of the Pu(VI) reduction with diformylhydrazine in a nitric acid medium was studied by spectrophotometry. The reaction rate increases with an increase in the reductant concentration and temperature and decreases with an increase in the HNO3 concentration. The reaction order with respect to Pu, diformylhydrazine, and HNO3 is 1, 1.3, and–1.5, respectively. The activation energy of the reaction is 86.9 kJ mol–1.
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About the authors
K. N. Dvoeglazov
Bochvar High-Tech Research Institute of Inorganic Materials
Author for correspondence.
Email: KNDvoeglazov@bochvar.ru
Russian Federation, ul. Rogova 5a, Moscow, 123060
E. Yu. Pavlyukevich
Bochvar High-Tech Research Institute of Inorganic Materials
Email: KNDvoeglazov@bochvar.ru
Russian Federation, ul. Rogova 5a, Moscow, 123060
P. V. Mitrikas
Bochvar High-Tech Research Institute of Inorganic Materials
Email: KNDvoeglazov@bochvar.ru
Russian Federation, ul. Rogova 5a, Moscow, 123060
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