High-temperature heat capacity of stannates Pr2Sn2O7 and Nd2Sn2O7


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Abstract

Oxide compounds Pr2Sn2O7 and Nd2Sn2O7 have been obtained by solid-phase synthesis. The effect of temperature on the heat capacity of Pr2Sn2O7 (360–1045 K) and Nd2Sn2O7 (360–1030 K) has been studied using differential scanning calorimetry. The thermodynamic properties of the compounds (changes in enthalpy, entropy, and the reduced Gibbs energy) have been calculated by the experimental data of Cp = f(T).

About the authors

L. T. Denisova

Institute of Nonferrous Metals and Material Science

Author for correspondence.
Email: antluba@mail.ru
Russian Federation, pr. imeni Gazety “Krasnoyarskii Rabochii” 95, Krasnoyarsk, 660025

L. A. Irtyugo

Institute of Nonferrous Metals and Material Science

Email: antluba@mail.ru
Russian Federation, pr. imeni Gazety “Krasnoyarskii Rabochii” 95, Krasnoyarsk, 660025

V. V. Beletskii

Institute of Nonferrous Metals and Material Science

Email: antluba@mail.ru
Russian Federation, pr. imeni Gazety “Krasnoyarskii Rabochii” 95, Krasnoyarsk, 660025

V. M. Denisov

Institute of Nonferrous Metals and Material Science

Email: antluba@mail.ru
Russian Federation, pr. imeni Gazety “Krasnoyarskii Rabochii” 95, Krasnoyarsk, 660025

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