Correlation of the properties of ionic conductivity–structure for the RbGaO2 solid electrolyte


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The crystal structure of rubidium gallate RbGaO2 in the temperature range of 300–853 K has been investigated using high-temperature neutron diffraction. The channels available for the motion of rubidium cations in the low-temperature and high-temperature modifications of RbGaO2 have been determined using the computer simulation with the TOPOS program. A correlation between the radius of the migration channel cross section and the rubidium cation conductivity has been established.

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N. Proskurnina

Institute of Metal Physics, Ural Branch

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Email: Proskurnina@imp.uran.ru
俄罗斯联邦, ul. Sofii Kovalevskoi 18, Yekaterinburg, 620990

V. Voronin

Institute of Metal Physics, Ural Branch

Email: Proskurnina@imp.uran.ru
俄罗斯联邦, ul. Sofii Kovalevskoi 18, Yekaterinburg, 620990

I. Berger

Institute of Solid State Chemistry, Ural Branch

Email: Proskurnina@imp.uran.ru
俄罗斯联邦, ul. Pervomaiskaya 91, Yekaterinburg, 620990

G. Shekhtman

Institute of High Temperature Electrochemistry, Ural Branch

Email: Proskurnina@imp.uran.ru
俄罗斯联邦, ul. Akademicheskaya 20, Yekaterinburg, 620990

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