Том 43, № 6 (2016)

The formation of snowmelt runoff from the Dzhankuat glacier has been considered and the hydrograph of the Dzhankuat R. has been separated with the use of isotope and ionic balance. Isotope variations of runoff at the outlet section of the Dzhankuat R. have been studied for two ablation seasons of 2013 and 2014. The separation of 2014 hydrograph was based on δ¹⁸O and mineralization values obtained for various sources of Dzhankuat R. recharge: precipitation, snow of different seasons, firn, ice, and groundwater. The isotopic separation of the hydrograph has shown that, in June, a considerable portion (15–20%) of Dzhankuat R. total runoff is due to the melting snow cover that has formed during spring snowfalls. In June, the proportion of this component in the total daily runoff can reach 36%. The contribution of the runoff originating from winter-snow melting varies from 20% in the early to 50% in the late June. In August and September, the share of groundwater varies from 30 to 100%; the share of precipitation, from 0 to 30% (on the average for the period, 6%); and the share of water from melting firn and ice, from 0 to 70% (on the average, 38.6%).

A semiempirical mathematical model of iron and manganese migration from bottom sediments into the water mass of water bodies has been proposed based on some basic regularities in the geochemistry of those elements. The entry of dissolved forms of iron and manganese under aeration conditions is assumed negligible. When dissolved-oxygen concentration is <0.5 mg/L, the elements start releasing from bottom sediments, their release rate reaching its maximum under anoxic conditions. The fluxes of dissolved iron and manganese (Me) from bottom sediments into the water mass (J_Me) are governed by the gradients of their concentrations in diffusion water sublayer adjacent to sediment surface and having an average thickness of h = 0.025 cm: \({J_{Me}} = - {D_{Me}}\frac{{{C_{Me\left( {ss} \right)}} - {C_{Me\left( w \right)}}}}{h}\) (D_Me ≈ 1 × 10^–9 m²/s is molecular diffusion coefficient of component Me in solution; C_Me(ss) and C_Me(w) ≈ 0 are Me concentrations on sediment surface, i.e., on the bottom boundary of the diffusion water sublayer, and in the water mass, i.e., on the upper boundary of the diffusion water sublayer). The value of depends on water saturation with dissolved oxygen (\({\eta _{{O_2}}}\)) in accordance with the empiric relationship \({C_{Me\left( {ss} \right)}} = \frac{{C_{_{Me\left( {ss} \right)}}^{\max }}}{{1 + k{\eta _{{O_2}}}}}\) (k is a constant factor equal to 300 for iron and 100 for manganese; C_Me(ss)^max is the maximal concentration of Me on the bottom boundary of the diffusion water sublayer with C_Fe(ss)^max ≈ 200 μM (11 mg/L), and C_Mn(ss)^max ≈ 100 μM (5.5 mg/L).

It is proposed to evaluate two theoretical characteristics, i.e., BOD (biochemical oxygen demand) and k₀ (the coefficient of oxidation rate by new formulas based on two experimental variables: BOD_T and BOD_2T (biochemical oxygen consumption in two periods T and 2T day, respectively). The formulation and an analytical solution are given for a direct problem describing the process of biochemical oxidation of organic matter (OM) in a water volume in the absence of aeration (e.g., in a water body under ice or in a sealed flask used to measure biochemical oxygen consumption). The problem is solved based on the closed (modified) Streeter–Phelps system. Unlike the classical Streeter–Phelps system, the closed system excludes physically incorrect solutions (e.g., negative concentrations of dissolved oxygen (DO)) [4]. The solution of the direct problem is used to formulate an inverse problem, whose solution is given in the form of formulas for evaluating BOD and k₀. These formulas are used to compile tables to illustrate the essence of the proposed method.

Variations in pan evaporation in European Russia from 1951 to 2010 have been studied, and regions with specific variations of potential evaporation have been identified. It is shown that evaporation decseases all over the territory under consideration, and intensity of its decreasing up to the late 1970s was far in excess of that in the decades that followed. The decrease in the variations in evaporation may be regarded as an indicator of reduction of intensity of heat and moisture exchange between the underlying surface and the atmosphere. A new characteristic of the moisture regime of the territory, i.e., visible evaporation, was introduced to characterize, in this case, the amount of free moisture in the atmosphere that can be involved in the terrestrial water cycle. The humidity of the territory in the European Russia has shown to have increased since 1966. Regions where changes in the moisture regime show common patterns have been identified and the specific features of humidity distribution in different natural zones of European Russia have been assessed.