The Influence of the Polymer Matrix on Luminescent Properties of Compositions Doped with Boron Chelates


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Luminescent polymer compositions based on polystyrene (PS), polycarbonate (PC), and polymethyl methacrylate (PMMA) doped with dibenzoylmethanate boron difluoride (DBMBF2), anthracene–acetonate boron difluoride (AntAcBF2), and their mixture have been investigated. The maximum quantum yield of luminescence has been demonstrated by the composition based on PS. The role of PS in increasing the efficiency of energy transfer from the donor (DBMBF2) to the acceptor (AntAcBF2) has been established and appeared to be caused by the formation of exciplexes of DBMBF2 with phenyl rings of PS.

作者简介

E. Fedorenko

Institute of Chemistry, Far East Branch, Russian Academy of Sciences

Email: xrebtov_aa@dvfu.ru
俄罗斯联邦, Vladivostok, 690022

A. Khrebtov

Far Eastern Federal University

编辑信件的主要联系方式.
Email: xrebtov_aa@dvfu.ru
俄罗斯联邦, Vladivostok, 690950

A. Mirochnik

Institute of Chemistry, Far East Branch, Russian Academy of Sciences

Email: xrebtov_aa@dvfu.ru
俄罗斯联邦, Vladivostok, 690022

P. Nefedov

Far Eastern Federal University

Email: xrebtov_aa@dvfu.ru
俄罗斯联邦, Vladivostok, 690950

L. Lim

Far Eastern Federal University

Email: xrebtov_aa@dvfu.ru
俄罗斯联邦, Vladivostok, 690950

V. Reutov

Far Eastern Federal University

Email: xrebtov_aa@dvfu.ru
俄罗斯联邦, Vladivostok, 690950

I. Pavlov

Far Eastern Federal University

Email: xrebtov_aa@dvfu.ru
俄罗斯联邦, Vladivostok, 690950

A. Sergeev

Institute of Automation and Control Processes, Far East Branch, Russian Academy of Sciences

Email: xrebtov_aa@dvfu.ru
俄罗斯联邦, Vladivostok, 690041

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