Email this article The Influence of the Polymer Matrix on Luminescent Properties of Compositions Doped with Boron Chelates
- Authors: Fedorenko E.V.1, Khrebtov A.A.2, Mirochnik A.G.1, Nefedov P.S.2, Lim L.A.2, Reutov V.A.2, Pavlov I.S.2, Sergeev A.A.3
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Affiliations:
- Institute of Chemistry, Far East Branch, Russian Academy of Sciences
- Far Eastern Federal University
- Institute of Automation and Control Processes, Far East Branch, Russian Academy of Sciences
- Issue: Vol 127, No 3 (2019)
- Pages: 459-462
- Section: Spectroscopy of Condensed States
- URL: https://ogarev-online.ru/0030-400X/article/view/166087
- DOI: https://doi.org/10.1134/S0030400X19090091
- ID: 166087
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Abstract
Luminescent polymer compositions based on polystyrene (PS), polycarbonate (PC), and polymethyl methacrylate (PMMA) doped with dibenzoylmethanate boron difluoride (DBMBF2), anthracene–acetonate boron difluoride (AntAcBF2), and their mixture have been investigated. The maximum quantum yield of luminescence has been demonstrated by the composition based on PS. The role of PS in increasing the efficiency of energy transfer from the donor (DBMBF2) to the acceptor (AntAcBF2) has been established and appeared to be caused by the formation of exciplexes of DBMBF2 with phenyl rings of PS.
About the authors
E. V. Fedorenko
Institute of Chemistry, Far East Branch, Russian Academy of Sciences
Email: xrebtov_aa@dvfu.ru
Russian Federation, Vladivostok, 690022
A. A. Khrebtov
Far Eastern Federal University
Author for correspondence.
Email: xrebtov_aa@dvfu.ru
Russian Federation, Vladivostok, 690950
A. G. Mirochnik
Institute of Chemistry, Far East Branch, Russian Academy of Sciences
Email: xrebtov_aa@dvfu.ru
Russian Federation, Vladivostok, 690022
P. S. Nefedov
Far Eastern Federal University
Email: xrebtov_aa@dvfu.ru
Russian Federation, Vladivostok, 690950
L. A. Lim
Far Eastern Federal University
Email: xrebtov_aa@dvfu.ru
Russian Federation, Vladivostok, 690950
V. A. Reutov
Far Eastern Federal University
Email: xrebtov_aa@dvfu.ru
Russian Federation, Vladivostok, 690950
I. S. Pavlov
Far Eastern Federal University
Email: xrebtov_aa@dvfu.ru
Russian Federation, Vladivostok, 690950
A. A. Sergeev
Institute of Automation and Control Processes, Far East Branch, Russian Academy of Sciences
Email: xrebtov_aa@dvfu.ru
Russian Federation, Vladivostok, 690041
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