The Influence of the Polymer Matrix on Luminescent Properties of Compositions Doped with Boron Chelates
- Авторы: Fedorenko E.V.1, Khrebtov A.A.2, Mirochnik A.G.1, Nefedov P.S.2, Lim L.A.2, Reutov V.A.2, Pavlov I.S.2, Sergeev A.A.3
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Учреждения:
- Institute of Chemistry, Far East Branch, Russian Academy of Sciences
- Far Eastern Federal University
- Institute of Automation and Control Processes, Far East Branch, Russian Academy of Sciences
- Выпуск: Том 127, № 3 (2019)
- Страницы: 459-462
- Раздел: Spectroscopy of Condensed States
- URL: https://ogarev-online.ru/0030-400X/article/view/166087
- DOI: https://doi.org/10.1134/S0030400X19090091
- ID: 166087
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Аннотация
Luminescent polymer compositions based on polystyrene (PS), polycarbonate (PC), and polymethyl methacrylate (PMMA) doped with dibenzoylmethanate boron difluoride (DBMBF2), anthracene–acetonate boron difluoride (AntAcBF2), and their mixture have been investigated. The maximum quantum yield of luminescence has been demonstrated by the composition based on PS. The role of PS in increasing the efficiency of energy transfer from the donor (DBMBF2) to the acceptor (AntAcBF2) has been established and appeared to be caused by the formation of exciplexes of DBMBF2 with phenyl rings of PS.
Об авторах
E. Fedorenko
Institute of Chemistry, Far East Branch, Russian Academy of Sciences
Email: xrebtov_aa@dvfu.ru
Россия, Vladivostok, 690022
A. Khrebtov
Far Eastern Federal University
Автор, ответственный за переписку.
Email: xrebtov_aa@dvfu.ru
Россия, Vladivostok, 690950
A. Mirochnik
Institute of Chemistry, Far East Branch, Russian Academy of Sciences
Email: xrebtov_aa@dvfu.ru
Россия, Vladivostok, 690022
P. Nefedov
Far Eastern Federal University
Email: xrebtov_aa@dvfu.ru
Россия, Vladivostok, 690950
L. Lim
Far Eastern Federal University
Email: xrebtov_aa@dvfu.ru
Россия, Vladivostok, 690950
V. Reutov
Far Eastern Federal University
Email: xrebtov_aa@dvfu.ru
Россия, Vladivostok, 690950
I. Pavlov
Far Eastern Federal University
Email: xrebtov_aa@dvfu.ru
Россия, Vladivostok, 690950
A. Sergeev
Institute of Automation and Control Processes, Far East Branch, Russian Academy of Sciences
Email: xrebtov_aa@dvfu.ru
Россия, Vladivostok, 690041
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