No 3 (2024)
Scientific articles
Isotopic composition of carbon and oxygen in Upper Carboniferous-Lower Permian carbonate rocks of the Losinoostrov Formation (Subpolar Urals, Kozhim River)
Abstract
The Paleozoic section on the Kozhim River of the Subpolar Urals is the best sequence of the northern Urals. The border of Carboniferous-Permian deposits are observed on the opposite banks of the Kozhim River and are represented by two types of sections: on the right bank — the Kozhym skeletal mound, on the left bank — depression deposits of mixed composition (Losinoostrov Fm.). The article presents the first information on the isotopic composition of carbon and oxygen in the Lower Permian limestones of the Losinoostrov Fm. It is shown that the obtained data on the isotopic composition on the ä13C–ä18O diagram are visually separated into three clusters. The first cluster with the lowest values of ä13C (–0.3…1.1 ‰) and ä18O (23.5…25.0 ‰) included the most intensively silicified rocks (siliceous bioclastic limestones, secondary silicitolites, siliceous-carbonate- argillaceous mixtolites and siliceous- argillaceous limestone). The third cluster, with the highest values of ä13C (3.9…5.1 ‰) and ä18O (26.0…26.8 ‰), includes bioclastic and peloid-micritic limestones. In this case, the ä13С values correspond to the range of variations in the carbon isotopic composition indicated in review works on the chemostratigraphic correlation of Permian deposits. The second cluster occupies an intermediate position and is characterized by the values of ä13C (2.0…2.8 ‰) and ä18O (24.3…25.4 ‰). This cluster is predominantly represented by limestones enriched with terrigenous materials.
A comparison is made of the isotopic composition of the limestones of the Losinoostrov Formation with the coeval limestones of the Kozhim skeletal mound, which showed higher values of ä13C and ä18O in the latter.



Effect of mineralizer and synthesis duration on sorption properties of sitinakite and ivanyukite
Abstract
Titanosilicates with the structure of sitinakite and ivanyukite were synthesized with the use of enrichment wastes of quartz-leucoxene concentrate (Yarega deposit, Komi Republic) by autoclave method. It was found that using a mixture of mineralizer KOH and NaOH at a concentration of 0.15 and 1 mol/l, K-Na sitinakite was formed. Increasing the concentration of KOH to 0.45 mol/L and decreasing NaOH to 0.7 mol/L led to crystallization of ivanyukite. The obtained titanosilicates are characterized by high sorption activity towards Sr2+ and Cs+ cations. Sorption capacity of K-Na sitinakite and ivanyukite for Sr2+ was 95–110 and 102–114 mg/g, respectively. The Cs+ sorption capacity for K-Na sitinakite is 240 mg/g, the sorption capacity for ivanyukite is much higher — 370–380 mg/g. It was shown that the differences in the sorption capacity of K-Na sitinakite and ivanyukite are caused by the features of the crystal structure.



From the Professor D. P. Grigoriev Archive: Professor A. Ya. Mickey’s letters
Abstract
This article completes the publication of the «Memories of Mineralogists» of the repressed Professor A. Ya. Mickey, found by the author in the Professor D. P. Grigoriev Archive, kept in the Russian Mineralogical Society. From the correspondence the motivations and life circumstances in which the texts were written become clear. A. Ya. Mickey’s letters are deciphered, attributed and briefly commented. The relevance of the article lies in the need to uphold the priorities of Russian science. The aim of the work is to cover as fully as possible the professional activities of repressed mineralogists as an important component of the history of Russian science. Mention of I. M. Beznarytny, A. K. Boldyrev, P. V. Bryantsev, V. I. Vernadsky, P. Groth, S. A. Zaborovsky, V. A. Zilbermints, L. L. Ivanov, E. P. Kastner, V. I. Kryzhanovsky, E. K. Lazarenko, N. I. Lebedev, A. V. Nechaev, I. I. Tanatar, V. V. Tikhomirov, E. K. Ustiev, N. M. Fedorovsky, G. K. Feldman, A. E. Fersman, P. N. Chirvinsky, and I. I. Shafranovsky should attract the attention of readers. Attention is drawn to the importance of personal archives in the study of the history of science. The of Professor D. P. Grigoriev Archive in letters and other documents reflects several decades of the pre-war and post-war history of Russian mineralogy.



On the question of the age of the Dzhezhim formation of the South Timan
Abstract
We have described jasper pebbles from gravelites of the Dzhezhim formation on the Zhezhimparma uplift in the Southern Timan. The chip has a zonal structure. The central part is composed of devitrified volcanic glass and is surrounded by the rocks with an oolitic and crustified structure, composed of hematite-pigmented microgranular hexagonal quartz aggregates. We made a conclusion that one of the sources of the detrital material was rocks of timanide (preuralide) orogen, which final collision stage was Late Vendian by the age.



Paleoproterozoic stromatolites Segosia columnaris and Sundosia mira of the Eastern part of the Fennoscandian Shield: microstructure and 3D modeling
Abstract
The purpose of this study is to study the microstructure and 3D modeling of Paleoproterozoic stromatolites Segosia columnaris and Sundosia mira in the eastern part of the Fennoscandian shield (Karelian craton). The premise of the study is the extensive paleontological material collected by researchers in the 1950s and 1980s. Modern methods, including SEM analysis, 3D modeling, and the results of Raman spectroscopy are used. As a result of studying the microstructure of stromatolites, possible remnants of cyanobacteria involved in the formation of these structures were identified, which potentially indicated the biogenic origin of the studied samples. The results of Raman spectroscopy obtained by other authors also indicate the biogenic nature of the studied samples.
For the first time, images of the spatial shapes of the studied stromatolites were obtained by 3D visualization software, which could be used to refine the classification of stromatolites by morphological features. 3D modeling of stromatolite buildings allowed restoring their original shape.



Chronicle, events, facts. History of Science
In memory of Vasily Nikolaevich Filippov
Abstract
Vasily Nikolaevich Filipov, Senior Researcher at the Laboratory of Experimental Mineralogy of the Institute of Geology FRC Komi SC UB RAS, died on March 3, 2024, at the age of 73. Vasily Nikolaevich was a highly qualified specialist who provided electron microscopic observations and microanalysis of minerals, artificial crystals and new materials at the most modern methodological level at the Institute of Geology. On the basis of V. N. Filippov’s researches complex problems of the genesis of a number of minerals — diamond, quartz, sphalerite, gold, fluorite — have been solved, and the ways for the rational use of various types of mineral raw materials of the Komi Republic have been outlined. He is the author of a number of inventions and discoveries in electron microscopy. He particularly discovered a new mode of operation of scanning electron microscopes, which significantly expanded possibilities of study of mineralogical objects, and a method for adjusting the position of the electron gun, a number of methods for metrological testing of the electron microscope was created. His original methods for preparing and mounting samples in an electron microscope are widely used in scientific laboratories and research centers in Russia. Vasily Nikolaevich was awarded the Certificate of Honor of the Ural Branch of the Russian Academy of Sciences (1998), the Certificate of Honor of the Trade Union of the Russian Academy of Sciences (1999), the Certificate of Honor from the Ministry of Natural Resources and Environmental Protection (2013) and the Certificate of Honor of the Komi Republic (2022), the Medal of the 2nd degree of the Order of Merit for the Fatherland (2002).


