A NEW MULTIFUNCTIONAL LUBRICANT ADDITIVE BASED ON A SULFUR-CONTAINING DERIVATIVE OF 2,6-DIMETHYLPHENOL

E. G. Bordubanova; Бордубанова Е. Г.; E. Yu. Oganesova; Оганесова Э. Ю.; A. S. Lyadov; Лядов А. С.; O. P. Parenago; Паренаго О. П.

doi:10.31857/S2686953523600290

A NEW MULTIFUNCTIONAL LUBRICANT ADDITIVE BASED ON A SULFUR-CONTAINING DERIVATIVE OF 2,6-DIMETHYLPHENOL

Авторлар: Bordubanova E.G.¹, Oganesova E.Y.¹, Lyadov A.S.¹, Parenago O.P.¹
Мекемелер:
1. A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Шығарылым: Том 512, № 1 (2023)
Беттер: 59-64
Бөлім: CHEMISTRY
URL: https://ogarev-online.ru/2686-9535/article/view/247182
DOI: https://doi.org/10.31857/S2686953523600290
EDN: https://elibrary.ru/XRSYCI
ID: 247182

Дәйексөз келтіру

Толық мәтін

Аннотация
Авторлар туралы
Әдебиет тізімі
Қосымша файлдар
Статистика

Аннотация

New dialkyldithio derivatives of 2,6-dimethylphenol have been synthesized and characterized. For the first time, the polyfunctional properties of these compounds have been studied as additives to lubricating oils in the processes of friction and wear in the boundary friction regime, as inhibitors of high-temperature oxidation of hydrocarbons, and as protectors of metal surfaces. It has been established that already with the content of synthesized additives in lubricating oils in the amount of 0.5 wt. % antiwear properties are improved more than twice. It has been shown that additives exhibit a complex antioxidant effect and high efficiency at all stages of the oxidation process, and even at ultra-low concentrations (0.005 wt. %), their ability to resist oxidation exceeds widely used analogs. New additives are of considerable interest to modern lubrication science, and they can be used in motor oil compositions and other lubricants.

Негізгі сөздер

2,6-dialkylphenol derivatives, dithiocarbamic acid derivatives, lubricating oil additives, friction and wear, antioxidant properties, anticorrosion properties

Әдебиет тізімі

Рудник Л.Р. Присадки к смазочным материалам. Свойства и применение. Пер. с англ. под ред. Данилова А.М. Санкт-Петербург: Профессия, 2013. 927 с. (Rudnick L.R. Lubricant Additives. Chemistry and Applications. Second Edition. London, New York: CRC Press Taylor & Francis Group, 2009).
Hörner D. // J. Synth. Lubrication. 2002. V. 18. № 4. P. 327–347. https://doi.org/10.1002/jsl.3000180407
Spikes H. // Tribol. Lett. 2004. V. 17. № 3. P. 469–489. https://doi.org/10.1023/B:TRIL.0000044495.26882.b5
Inoue K., Kurahashi T., Negishi T., Akiyama T., Arimura K., Tasaka K. // SAE Technical Paper. 1992. P. 920654. https://doi.org/10.4271/920654
Koltsakis G.C., Stamatelos A.M. // Prog. Energy Combust. Sci. 1997. V. 23. № 1. P. 1–39. https://doi.org/10.1016/S0360-1285(97)00003-8
Kumar S.V., Rogalo J., Deeba M., Burk P.L., Ferrari V. // SAE Technical Paper. 2003. P. 2003-01-3735. https://doi.org/10.4271/2003-01-3735
Franz J., Schmidt J., Schoen C., Harpersheid M., Eckhoff S., Roesch M., Leyrer J. // SAE Technical Paper. 2005. P. 2005-01-1097. https://doi.org/10.4271/2005-01-1097
Spikes H. // Lubrication Sci. 2008. V. 20. № 2. P. 103–136. https://doi.org/10.1002/ls.57
Паренаго О.П., Оганесова Э.Ю., Лядов А.С., Шараева А.А. // Журн. прикл. хим. 2020. Т. 93. № 11. С. 1523–1542. https://doi.org/10.31857/S0044461820110018
Переслегина Н.С., Кузьмина Г.Н., Маркова Е.И., Санин П.И. // Нефтехимия. 1986. Т. 26. № 4. С. 563–570.
Переслегина Н.С., Кузьмина Г.Н., Дзюбина М.А., Санин П.И. // Нефтехимия. 1988. Т. 28. № 6. С. 813–822.