Phthalates in the snow cover of the Selenga River basin: content, sources and spatial distribution

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

The content and spatial distribution of six priority phthalates in the snow cover of the city of UlanUde were studied for the first time. Ulan-Ude is located in the basin of the Selenga River, the main tributary of Lake Baikal. Snow samples were collected before the spring melting at 17 points located in the floodplains of the Selenga and Uda rivers and in the zones affected by various pollution sources. The snow water was analyzed by the gas chromatography-mass spectrometry (GC-MS) method. The analysis showed that the total content of phthalates varied from 0.76 to 9.09 μg/L. Dibutyl phthalate, di-(2-ethylhexyl) phthalate, and diethyl phthalate are dominant compounds. The obtained results on the distribution of phthalates in the snow cover within the urban agglomeration showed a slightly different dynamic of the accumulation from the previously studied pollutants. The highest contents were revealed in places with a high transport load in the zones of solid waste landfills characterized by natural depressions in the relief. Although the level of air pollution in Ulan-Ude is assessed as very high, the content of phthalates in the snow cover is significantly lower than that noted in other cities. Analysis of the phthalate content in the snow cover in Ulan-Ude is important for assessing the contribution of atmospheric sources to water pollution.

About the authors

O. D. Budaeva

Baikal Institute of Nature Management, Siberian Branch of the Russian Academy of Sciences

Email: olga.budaeva1985@mail.ru
Ulan-Ude, Russia

S. V. Bazarsadueva

Baikal Institute of Nature Management, Siberian Branch of the Russian Academy of Sciences

Ulan-Ude, Russia

E. P. Nikitina

Baikal Institute of Nature Management, Siberian Branch of the Russian Academy of Sciences

Ulan-Ude, Russia

S. V. Zhigzhitzhapova

Baikal Institute of Nature Management, Siberian Branch of the Russian Academy of Sciences

Ulan-Ude, Russia

V. G. Shiretorova

Baikal Institute of Nature Management, Siberian Branch of the Russian Academy of Sciences

Ulan-Ude, Russia

N. B. Nimbueva

Baikal Institute of Nature Management, Siberian Branch of the Russian Academy of Sciences

Ulan-Ude, Russia

V. V. Taraskin

Baikal Institute of Nature Management, Siberian Branch of the Russian Academy of Sciences

Ulan-Ude, Russia

L. D. Radnaeva

Baikal Institute of Nature Management, Siberian Branch of the Russian Academy of Sciences

Ulan-Ude, Russia

E. Z. Garmaev

Baikal Institute of Nature Management, Siberian Branch of the Russian Academy of Sciences

Ulan-Ude, Russia

A. K. Tulokhonov

Baikal Institute of Nature Management, Siberian Branch of the Russian Academy of Sciences

Ulan-Ude, Russia

References

  1. Lyche J.L. Phthalates. In Reproductive and Developmental Toxicology, 2nd ed.; Gupta, R.C., Ed.; Cambridge, MA, USA: Academic Press, 2017. P. 829–856. https://doi.org/10.1016/B978-0-12-804239-7.00044-5
  2. Vasseghian Y., Alimohamadi M., Dragoi E., Sonne C. A global meta-analysis of phthalate esters in drinking water sources and associated health risks // Science of The Total Environment. 2023. V. 903. P. 166846. https://doi.org/10.1016/j.scitotenv.2023.166846
  3. Zhang Y., Jiao Y., Li Z. et al. Hazards of phthalates (PAEs) exposure: A review of aquatic animal toxicology studies // Science of The Total Environment. 2021. V. 771. P. 145418. https://doi.org/10.1016/j.scitotenv.2021.145418
  4. Mazur D.M., Latkin T.B., Kosyakov D.S. et al. Arctic snow pollution: A GC-HRMS case study of Franz Joseph Land archipelago // Environmental Pollution. 2020. V. 265 (B). P. 114885. https://doi.org/10.1016/j.envpol.2020.114885
  5. Gomboev B.O., Dambueva I.K., Khankhareev S.S. et al. Atmospheric Air Pollution by Stationary Sources in Ulan-Ude (Buryatia, Russia) and Its Impact on Public Health // International Journal of Environmental Research and Public Health. 2022. V. 19. P. 16385. https://doi.org/10.3390/ijerph192416385
  6. Обзор состояния и загрязнения окружающей среды в Российской Федерации за 2023 год. М., 2024. 215 с.
  7. Lebedev A.T., Mazur D.M., Polyakova O.V., Hänninen O. Snow Samples as Markers of Air Pollution in Mass Spectrometry Analysis. In Environmental Indicators; Armon R., Hänninen O., Eds.; Dordrecht: Springer, 2014. P. 515–541. https://doi.org/10.1007/978-94-017-9499-2_31
  8. Taraskin V.V., Budaeva O.D., Nikitina E.P. et al. Phthalates in Surface Waters of the Selenga River (Main Tributary of Lake Baikal) and Its Delta: Spatial-Temporal Distribution and Environmental Risk Assessment // Water. 2024. V. 16(4). P. 525. https://doi.org/10.3390/w16040525
  9. Bazarsadueva S.V., Taraskin V.V., Budaeva O.D. et al. First Data on PAE Levels in Surface Water in Lakes of the Eastern Coast of Baikal // International Journal of Environmental Research and Public Health. 2023. V. 20. P. 1173. https://doi.org/10.3390/ijerph20021173
  10. Lebedev A.T., Polyakova O.V., Mazur D.M. et al. Estimation of contamination of atmosphere of Moscow in winter // Journal of Analytical Chemistry. 2012. V. 67. No 14. P. 1039–1049. https://doi.org/10.1134/S1061934812140079
  11. Růžičková J., Raclavská H., Kucbel M. et al. Incidence and spread of additives from co-combustion of plastic waste in domestic boilers in indoor and outdoor environments around the family house // Energy. 2023. V. 285. P. 129357. https://doi.org/10.1016/j.energy.2023.129357
  12. Vasiljevic T., Su K., Harner T. A first look at atmospheric concentrations and temporal trends of phthalates in distinct urban sectors of the Greater Toronto Area // Atmospheric Pollution Research. 2021. V. 12. P. 173–182. https://doi.org/10.1016/j.apr.2020.10.019
  13. Llompart M., Sanchez-Prado L., Pablo Lamas J. et al. Hazardous organic chemicals in rubber recycled tire playgrounds and pavers // Chemosphere. 2013. V. 90. P. 423–431. https://doi.org/10.1016/j.chemosphere.2012.07.053
  14. Sarasa J., Llabrés T., Ormad P. et al. Characterization and photo-Fenton treatment of used tires leachate // Journal of Hazardous Materials. 2006. V. 136. P. 874–881. https://doi.org/10.1016/j.jhazmat.2006.01.023
  15. Эколого-географический атлас-монография «Селенга-Байкал». Касимов Н.С. (ред.). М.: Географический факультет МГУ, 2019. 288 с.
  16. Lebedev A., Nikolaeva S., Poliakova O. et al. Metals and organic pollutants in snow surrounding an iron factory // Environmental Chemistry Letters. 2003. V. 1. P. 107–112. https://doi.org/10.1007/s10311-002-0004-5
  17. Усков Т.Н., Малыгина Н.С., Папина Т.С. Загрязнение фталатами снежного покрова поймы р. Обь в районе г. Барнаула // Вода: химия и экология. 2016. Т. 1(91). С. 11–17.
  18. Mazur D.M., Sosnova A.A., Latkin T.B. et al. Application of clusterization algorithms for analysis of semivolatile pollutants in Arkhangelsk snow // Analytical and Bioanalytical Chemistry. 2023. V. 415. P. 2587–2599. https://doi.org/10.1007/s00216-022-04390-z
  19. Müller A., Österlund H., Marsalek J., Viklander M. Exploiting urban road side snowbanks as passive samplers of organic micropollutants and metals generated by traffic // Environmental Pollution. 2022. V. 308. P. 119723. https://doi.org/10.1016/j.envpol.2022.119723

Supplementary files

Supplementary Files
Action
1. JATS XML

Copyright (c) 2025 Russian Academy of Sciences

Согласие на обработку персональных данных

 

Используя сайт https://journals.rcsi.science, я (далее – «Пользователь» или «Субъект персональных данных») даю согласие на обработку персональных данных на этом сайте (текст Согласия) и на обработку персональных данных с помощью сервиса «Яндекс.Метрика» (текст Согласия).