Dehydrogenation of Hydrocarbons in Catalytic Membrane Reactors with Selective Hydrogen Extraction on Palladium-Containing and PNBI Membranes

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

The paper considers the features of the processes of dehydrogenation of aliphatic and alkylaromatic hydrocarbons in a catalytic membrane reactor, in which, in addition to the stage of chemical transformation of reagents into reaction products, there is a stage of separation of the obtained products on a hydrogen-selective membrane on the catalyst. For the separation stage, in the first case, a dense membrane made of a palladium-ruthenium alloy twisted into an elastic spring was used, which was placed directly in the hot zone of the reactor (600°C). In the second case, a sequential gas separation module with a non-porous polymer film membrane of the polynaphthoylene benzimidazole (PNBI)-σ type was used, operating at a reduced temperature (250°C).

Авторлар туралы

A. Fedotov

A. V. Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences

Email: alexey.fedotov@ips.ac.ru
Moscow, Russian Federation

D. Grachev

A. V. Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences

Moscow, Russian Federation

A. Alentyev

A. V. Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences

29 Moscow, Russian Federation

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