Selection of Anion Exchange Membranes for Optimization of Electrodialytic Extraction of Tartrates from Aqueous Solutions

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Resumo

The challenge of extracting organic acids using membrane technologies highlights the critical issue of reducing production costs and improving environmental efficiency in food and medical industries. Organic acids play a key role in manufacturing a wide range of products. Electrodialysis (ED) has established itself as a highly efficient, environmentally friendly, and economical extraction method, particularly for tartrates. During extensive testing focused on extracting tartrates from solutions via electrodialysis, a comparative study of three types of ion-exchange membranes was conducted: ASE, CJMA-3, and MA-41P. Results showed significant differences in efficiency and energy consumption among these membranes. Data were obtained in NaxH(2–x)T solution with pH 3.0, characterized by the maximum molar fraction of monovalent tartrate anions. It was demonstrated that the ASE membrane exhibits inferior mass transfer characteristics and higher energy consumption during the electrodialytic extraction of tartrates compared to the CJMA-3 membrane, despite having the highest experimental limiting current values. The MA-41P membrane, in turn, demonstrates high mechanical strength, resistance to damage, and extended service life. However, its efficiency in tartrate extraction over the same electrodialysis period proved lower than that of the CJMA-3 membrane. Thus, CJMA-3 is preferable for ED processing of tartrate-containing solutions.

Sobre autores

O. Yurchenko

Kuban State University

Email: olesia93rus@mail.ru
149 Stavropol str., Krasnodar, 350040, Russia

K. Brizhan

Kuban State University

149 Stavropol str., Krasnodar, 350040, Russia

N. Pismenskaya

Kuban State University

149 Stavropol str., Krasnodar, 350040, Russia

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