Heat processes in mixtures of polymers with cyanuric acid after plastic deformation under high pressure according to calorimetric data


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Mixtures of cyanuric acid with different polymers are subjected to plastic deformation under pressure of 1 GPa, and the DSC method is used to establish that endothermal processes with enthalpies that can reach 50 J g-1 occur in deformed mixtures under heating in the range of 50–250°C. The occurrence of endothermal processes is related to the destruction of intermolecular bonds formed at the acid–polymer interface and due to formation of double electric layers and appearance of interphase electrostatic attraction.

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V. Zhorin

Semenov Institute of Chemical Physics

编辑信件的主要联系方式.
Email: vzhorin@mail.ru
俄罗斯联邦, ul. Kosygina 4, Moscow, 119991

M. Kiselev

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: vzhorin@mail.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 117915

V. Kotenev

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: vzhorin@mail.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 117915

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