Отправить статью по E-mail Heat processes in mixtures of polymers with cyanuric acid after plastic deformation under high pressure according to calorimetric data
- Авторы: Zhorin V.A.1, Kiselev M.R.2, Kotenev V.A.2
-
Учреждения:
- Semenov Institute of Chemical Physics
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Выпуск: Том 52, № 5 (2016)
- Страницы: 876-880
- Раздел: New Substances, Materials, and Coatings
- URL: https://ogarev-online.ru/2070-2051/article/view/203414
- DOI: https://doi.org/10.1134/S2070205116050270
- ID: 203414
Цитировать
Открытый доступ
Доступ предоставлен
Только для подписчиков
Аннотация
Mixtures of cyanuric acid with different polymers are subjected to plastic deformation under pressure of 1 GPa, and the DSC method is used to establish that endothermal processes with enthalpies that can reach 50 J g-1 occur in deformed mixtures under heating in the range of 50–250°C. The occurrence of endothermal processes is related to the destruction of intermolecular bonds formed at the acid–polymer interface and due to formation of double electric layers and appearance of interphase electrostatic attraction.
Об авторах
V. Zhorin
Semenov Institute of Chemical Physics
Автор, ответственный за переписку.
Email: vzhorin@mail.ru
Россия, ul. Kosygina 4, Moscow, 119991
M. Kiselev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: vzhorin@mail.ru
Россия, Leninskii pr. 31, Moscow, 117915
V. Kotenev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: vzhorin@mail.ru
Россия, Leninskii pr. 31, Moscow, 117915
Дополнительные файлы
