A stable aqueous dispersion of polyaniline and polymeric acid


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Resumo

Conditions that allow obtaining stable aqueous dispersions based on conducting polymer, polyaniline, as a result of aniline polymerization in the solution of polymeric acid at its twofold excess were determined. The electrical and optical properties of polianiline obtained under these conditions remain invariable during at least 2 years due to the absence of aggregation of conducting polymer particles that are separated by macromolecules of polymeric acid. Data obtained by EPR spectroscopy, SEM, UV–visible spectroscopy, and IR spectroscopy prove these results.

Sobre autores

O. Iakobson

A. N. Frumkin Institute of Physical Chemistry and Electrochemistry

Autor responsável pela correspondência
Email: iakobson.olga@yandex.ru
Rússia, pr. Leninskiy 31, Moscow, 119071

O. Gribkova

A. N. Frumkin Institute of Physical Chemistry and Electrochemistry

Email: iakobson.olga@yandex.ru
Rússia, pr. Leninskiy 31, Moscow, 119071

A. Nekrasov

A. N. Frumkin Institute of Physical Chemistry and Electrochemistry

Email: iakobson.olga@yandex.ru
Rússia, pr. Leninskiy 31, Moscow, 119071

V. Tverskoi

Moscow Technological University

Email: iakobson.olga@yandex.ru
Rússia, pr. Vernadskogo 78, Moscow, 119454

V. Ivanov

A. N. Frumkin Institute of Physical Chemistry and Electrochemistry

Email: iakobson.olga@yandex.ru
Rússia, pr. Leninskiy 31, Moscow, 119071

P. Mel’nikov

Moscow Technological University

Email: iakobson.olga@yandex.ru
Rússia, pr. Vernadskogo 78, Moscow, 119454

E. Polenov

Moscow Technological University

Email: iakobson.olga@yandex.ru
Rússia, pr. Vernadskogo 78, Moscow, 119454

A. Vannikov

A. N. Frumkin Institute of Physical Chemistry and Electrochemistry

Email: iakobson.olga@yandex.ru
Rússia, pr. Leninskiy 31, Moscow, 119071

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