Oxidation temperatures of WC-Co cemented tungsten carbides

Introduction. Products containing WC-Co cemented tungsten carbides are commonly used in various industries. It is often operates at elevated temperatures, at which, as noted in the literature, tungsten carbides are susceptible to severe oxidation in air. However, no sufficiently accurate values of oxidation temperatures and dependence of these temperatures and the oxidation rate of tungsten carbides on the cobalt content with its wide variation have been established. The subject of the study is the oxidation process of WC-Co cemented tungsten carbides. The purpose of the work is to obtain the oxidation temperatures of WC-Co cemented tungsten carbides with different cobalt content by weight in the range of 3–20 %. Methods. The dynamics of oxidation was studied in air. Specimens of the same length were heated to a temperature of 850 °C and cooled at the same rate in the furnace of a push-rod dilatometer Netzsch 402 PC while its expansion was simultaneously recorded. The oxidation rate of the specimens was determined by the difference in its length before heating and after cooling. The values of oxidation temperatures were obtained by mathematical analysis of relationships of the expansion on temperature. Results and discussion. Experimental dependences of expansion of WC-Co cemented tungsten carbides on temperature in the range from 20 to 850 °C, and for WC-8Co – up to 1,150 °C, were obtained. The oxidation rate of WC-Co cemented tungsten carbides increased linearly with increasing concentration of tungsten carbides (decreased with increasing cobalt content). During heating, two characteristic temperatures were identified: the onset of oxidation (631±4 °C) and the transition to active oxidation (804±11 °C). The established temperatures were the same for different ratios of tungsten carbides and cobalt. The results can be used when choosing temperature conditions for products made from WC-Co cemented tungsten carbides.

Elevated temperatures, High-temperature oxidation, Tungsten cemented carbides, WC-Co, Dilatometry, Thermal expansion, Temperature of oxidation, Gas corrosion, Chemical destruction