Catalysts for oxygen electroreduction in alkaline medium based on carbon nanotubes modified with urea and phthalocyanines of iron, cobalt and palladium

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Дәйексөз келтіру

Толық мәтін

Аннотация

Catalysts for oxygen reduction in the alkaline electrolyte based on multi-walled carbon nanotubes modified with urea and phthalocyanines of iron, cobalt and palladium were synthesized and studied. Physicochemical studies of the surface of the synthesized materials were carried out using porosimetry, Raman spectroscopy, X-ray phase analysis and X-ray photoelectron spectroscopy. The catalyst doped with metal phthalocyanines (MWCNT(Urea)_CoPc_FePc_Pd) has the largest surface area. It can be assumed that the high specific surface area of this catalyst is obtained due to the formation of new layers of hierarchical carbon on the surface of the nanotubes during high-temperature pyrolysis. It was established that metal phthalocyanines are nitrogen dopants in the structure of carbon nanotubes. The electrocatalytic properties of the synthesized catalysts in the oxygen reduction reaction were studied using the voltammetric method.

Авторлар туралы

Kirill Vinogradov

Samara National Research University

ORCID iD: 0000-0001-5576-6247
34 Moskovskoe shosse

Vladislav Davydov

Samara National Research University

34 Moskovskoe shosse

Elena Tokranova

Samara National Research University

ORCID iD: 0000-0002-0568-1509
34 Moskovskoe shosse

Roman Shafigulin

Samara National Research University

ORCID iD: 0000-0001-9981-1249
34 Moskovskoe shosse

Sergei Vostrikov

Samara National Research University; Samara State Technical University

ORCID iD: 0000-0003-1102-473X
34 Moskovskoe shosse

Andzhela Bulanova

Samara National Research University

ORCID iD: 0000-0001-6243-8444
34 Moskovskoe shosse

Әдебиет тізімі

  1. Jiang Y., Yang L., Sun T., Zhao J., Lyu Z., Zhuo O., Wang X., Wu Q., Ma J., Hu Z. Significant contribution of intrinsic carbon defects to oxygen reduction activity. ACS Catalysis, 2015, vol. 5, iss. 11, pp. 6707– 6712. https://doi.org/10.1021/acscatal.5b01835
  2. Yan X., Jia Y., Yao X. Defects on carbons for electrocatalytic oxygen reduction. Chemical Society Reviews, 2018, vol. 47, iss. 20, pp. 7628–7658. https://doi.org/10.1039/c7cs00690j
  3. Singh S. K., Takeyasu K., Nakamura J. Active sites and mechanism of oxygen reduction reaction electrocatalysis on nitrogen-doped carbon materials. Advanced Materials, 2019, vol. 31, iss. 13, art. e1804297. https://doi.org/10.1002/adma.201804297
  4. Lu H. J., Li Y., Zhang L. Q., Li H. N., Zhou X., Liu A. R., Zhang Y. J., Liu S. Q. Synthesis of B-doped hollow carbon spheres as efficient non-metal catalyst for oxygen reduction reaction. RSC Advances, 2015, vol. 5, iss. 64, pp. 52126–52131. https://doi.org/10.1039/c5ra07909h
  5. Sun Y., Wu J., Tian J., Jin C., Yang R. Sulfurdoped carbon spheres as efficient metal-free electrocatalysts for oxygen reduction reaction. Electrochimica Acta, 2015, vol. 178, pp. 806–812. https://doi.org/10.1016/j.electacta.2015.08.059
  6. Wu J., Yang Z., Sun Q., Li X., Strasser P., Yang R. Synthesis and electrocatalytic activity of phosphorus-doped carbon xerogel for oxygen reduction. Electrochimica Acta, 2014, vol. 127, pp. 53–60. https://doi.org/10.1016/j.electacta.2014.02.016
  7. Wu B., Meng H., Morales D. M., Zeng F., Zhu J., Wang B., Risch M., Xu Z. J., Petit T. Nitrogen‐rich carbonaceous materials for advanced oxygen electrocatalysis: Synthesis, characterization, and activity of nitrogen sites. Advanced Functional Materials, 2022, vol. 32, iss. 31, art. 2204137. https://doi.org/10.1002/adfm.202204137
  8. Guo K., Li N., Bao L., Zhang P., Lu X. Intrinsic carbon structural imperfections for enhancing energy conversion electrocatalysts. Chemical Engineering Journal, 2023, vol. 466, art. 143060. https://doi.org/10.1016/j.cej.2023.143060
  9. Wang T., Chutia A., Brett D. J., Shearing P. R., He G., Chai G., Parkin I. P. Palladium alloys used as electrocatalysts for the oxygen reduction reaction. Energy & Environmental Science, 2021, vol. 14, iss. 5, pp. 2639–2669. https://doi.org/10.1039/d0ee03915b
  10. Jiang S., Zhu C., Dong S. Cobalt and nitrogencofunctionalized graphene as a durable non-precious metal catalyst with enhanced ORR activity. Journal of Materials Chemistry. A, 2013, vol. 1, iss. 11, pp. 3593– 3599. https://doi.org/10.1039/c3ta01682j
  11. Zhang Z., Sun J., Wang F., Dai L. Efficient oxygen reduction reaction (ORR) catalysts based on single iron atoms dispersed on a hierarchically structured porous carbon framework. Angewandte Chemie, 2018, vol. 130, iss. 29, pp. 9176–9181. https://doi.org/10.1002/ange.201804958
  12. Li X., Wang Z., Su Z., Zhao Z., Cai Q., Zhao J. Phthalocyanine-supported single-atom catalysts as a promising bifunctional electrocatalyst for ORR/OER: A computational study. ChemPhysMater, 2022, vol. 1, iss. 3, pp. 237–245. https://doi.org/10.1016/j.chphma.2022.04.002
  13. Liang Z., Wang H. Y., Zheng H., Zhang W., Cao R. Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide. Chemical Society Reviews, 2021, vol. 50, iss. 4, pp. 2540–2581. https://doi.org/10.1039/d0cs01482f
  14. Mei Z. Y., Cai S., Zhao G., Zou X., Fu Y., Jiang J., An Q., Li M., Liu T., Guo H. Boosting the ORR active and Zn-air battery performance through ameliorating the coordination environment of iron phthalocyanine. Chemical Engineering Journal, 2022, vol. 430, art. 132691. https://doi.org/10.1016/j.cej.2021.132691
  15. Hebié S., Bayo-Bangoura M., Bayo K., Servat K., Morais C., Napporn T. W., Boniface Kokoh K. Electrocatalytic activity of carbon-supported metallophthalocyanine catalysts toward oxygen reduction reaction in alkaline solution. Journal of Solid State Electrochemistry, 2016, vol. 20, iss. 4, pp. 931–942. https://doi.org/10.1007/s10008-015-2932-6
  16. Thommes M., Kaneko K., Neimark A. V., Olivier J. P., Rodriguez-Reinoso F., Rouquerol J., Sing K. S. Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure and Applied Chemistry, 2015, vol. 87, iss. 9-10, pp. 1051–1069. https://doi.org/10.1515/pac-2014-1117
  17. Sadezky A., Muckenhuber H., Grothe H., Niessner R., Pöschl U. Raman microspectroscopy of soot and related carbonaceous materials: Spectral analysis and structural information. Carbon, 2005, vol. 43, iss. 8, pp. 1731–1742. https://doi.org/10.1016/j.carbon.2005.02.018
  18. Zhang H. B., Lin G. D., Zhou Z. H., Dong X., Chen T. Raman spectra of MWCNTs and MWCNTbased H2-adsorbing system. Carbon, 2002, vol. 40, iss. 13, pp. 2429–2436. https://doi.org/10.1016/s0008-6223(02)00148-3
  19. Zhang J. X., Yang X. L., Shao H. F., Tseng C. C., Wang D. S., Tian S. S., Hu W. J., Jing C., Tian J. N., Zhao Y. C. Microwave-assisted synthesis of pd oxide-rich pd particles on nitrogen/sulfur co-doped graphene with remarkably enhanced ethanol electrooxidation. Fuel Cells, 2017, vol. 17, iss. 1, pp. 115–122. https://doi.org/10.1002/fuce.201600153
  20. Zhu M., Diao G. Synthesis of porous Fe3O4 nanospheres and its application for the catalytic degradation of xylenol orange. The Journal of Physical Chemistry C, 2011, vol. 115, iss. 39, pp. 18923–18934. https://doi.org/10.1021/jp200418j
  21. Buğday N., Altin S., Yaşar S. Porous carbon‐supported CoPd nanoparticles: High‐performance reduction reaction of nitrophenol. Applied Organometallic Chemistry, 2022, vol. 36, iss. 8, art. e6797. https://doi.org/10.1002/aoc.6797
  22. Ma M., Zhu W., Shao Q., Shi H., Liao F., Shao C., Shao M. Palladium–copper bimetallic nanoparticles loaded on carbon black for oxygen reduction and zinc–air batteries. ACS Applied Nano Materials, 2021, vol. 4, iss. 2, pp. 1478–1484. https://doi.org/10.1021/acsanm.0c02997

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