Preparation of polymer electrolytes based on polyurethane elastomer by the swelling method

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The search for solvents to prepare polymer electrolytes based on polyurethane elastomer by swelling method was carried out. The greatest swelling was observed in N-methyl-2-pyrrolidone, and the maximum degree of swelling was reached in 24 hours at 25°C. The swelling effect decreased with increasing the salt concentration. The ionic conductivity of the polymer electrolytes reached the maximum of 6–8·10-4 S/cm at 5 wt% of lithium salt. Using the method of galvanostatic cycling it was shown that the electrolyte was reversible by lithium ions and electrochemically stable in the voltage range up to 4.8 V

Sobre autores

Nikita Fedorov

Institute of Chemistry of a Solid body and Mechanochemistry of the Siberian Branch of RAS

ORCID ID: 0009-0000-9192-2075
18, Kutateladze St., Novosibirsk, 630128

Nikolai Uvarov

Institute of Chemistry of a Solid body and Mechanochemistry of the Siberian Branch of RAS

ORCID ID: 0000-0002-8209-7533
Código SPIN: 8137-4513
18, Kutateladze St., Novosibirsk, 630128

Artem Ulihin

Institute of Chemistry of a Solid body and Mechanochemistry of the Siberian Branch of RAS

ORCID ID: 0000-0002-6795-0006
Código SPIN: 2810-7309
Scopus Author ID: 15046088200
Researcher ID: P-1187-2017
18, Kutateladze St., Novosibirsk, 630128

Bibliografia

  1. hargeable Li batteries. Chemistry of Materials, 2010, vol. 22, no. 3, pp. 587–603. https://doi.org/10.1021/cm901452z
  2. Fergus J. W. Ceramic and polymeric solid electrolytes for lithium-ion batteries. J. Power Sources, 2010, vol. 195, no. 15, pp. 4554–4569. https://doi.org/10.1016/j.jpowsour.2010.01.076
  3. Barteau K. P., Wolffs M., Lynd N. A., Fredrickson G. H., Kramer E. J., Hawker C. J. Allyl glycidyl ether-based polymer electrolytes for room temperature lithium batteries. Macromolecules, 2013, vol. 46, no. 22, pp. 8988–8994. https://doi.org/10.1021/ma401267w
  4. Sun B., Mindemark J., Edstrom K., Brandell D. Polycarbonate-based solid polymer electrolytes for Liion batteries. Solid State Ionics, 2014, vol. 262, pp. 738– 742. https://doi.org/10.1016/j.ssi.2013.08.014
  5. Andersson R., Hernández G., See J., Flaim T. D., Brandell D., Mindemark J. Designing polyurethane solid polymer electrolytes for hightemperature lithium metal batteries. ACS Applied Energy Materials, 2022, vol. 5, no. 1, pp. 407–418. https://doi.org/10.1021/acsaem.1c02942
  6. Adolf E. Equilibrium swelling of polyurethane elastomer. Rubber Chemistry and Technology, 1990, vol. 63, no. 1, pp. 56–65. https://doi.org/10.5254/1.3538242
  7. Nierzwicki W., Majewska Z. Swelling properties of urethane elastomer and their bearing on microphase separation. J. Applied Polymer Science, 1979, vol. 24, pp. 1089–1099. https://doi.org/10.1002/app.1979.070240421
  8. Shibayama K., Kodaria M. Effects of concentration of urethane linkage, crosslinking density, and swelling upon the viscoelastic properties of polyurethanes. J. Polymer Science, 1966, vol. 4, pp. 83– 108. https://doi.org/10.1002/pol.1966.150040106

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