Vol 24, No 1 (2024)

Articles

Supercapacitors produced by industrial companies

Vol'fkovich Y.M.

Abstract

The review of modern scientific and technical literature on supercapacitors produced by industrial companies is presented. The advantages of supercapacitors compared to batteries are: high power density, high cycleability, the ability to operate at extreme temperatures from –50 to +60°C, energy efficiency up to 100% and the ability to charge in a very short time. The review examines the characteristics of supercapacitors manufactured by the following companies: Maxwell Technologies (California, USA), NessCap (Republic of Korea), ApowerCap (California, USA), Skeleton Technologies (Germany, Estonia), EPCOS (Munich, Germany), Panasonic (Osaka, Japan), Fuji Heavy (Shibuya, Japan), Asahi Glass (Tokyo, Japan), ESMA (Moscow region, Russian Federation). The characteristics considered in the article include specific energy, power density, full discharge time, full charge time, discharge efficiency, the number of full cycles, rated voltage and temperature range.
Electrochemical Energetics. 2024;24(1):3-27
pages 3-27 views

Effect of lithium perchlorate concentration on lithium cation transference number in sulpholane solutions

Savvina A.A., Karaseva E.V., Mochalov S.E., Kolosnitsyn V.S.

Abstract

To increase the accuracy of determining the lithium cation transference numbers we proposed to measure them at different values of the polarizing voltage and extrapolate the calculated values to the zero value of the polarizing voltage. It was established that the lithium cation transference numbers increased linearly with the increasing concentration of LiClO4 solutions in sulfolane. It is assumed that the increase in the lithium cation transference numbers takes place due to the change in lithium perchlorate state in sulfolane solution and the mechanism of ion transfer. It was shown that the maximum cation conductivity was achieved at the concentration of lithium perchlorate sulfolane solution of about 2M.
Electrochemical Energetics. 2024;24(1):28-37
pages 28-37 views

Oxygen biocathode based on laccase Pleurotus ostreatus HK-35 for biofuel cell

Meshherjakova M.O., Filippova M.V., Burygin G.L., Kazarinov I.A.

Abstract

The main reasons that make mankind look for new sources of energy are decreasing dependence on fossil fuels and reducing pollution. Wastewater treatment with the help of microbial fuel cells is an area where these two goals can be combined. Microbial fuel cells, in which microorganisms catalyze the oxidation of organic substances, represent a new and promising alternative for electricity generation. The creation of an efficient cathode in such systems is the important problem. It is evident that in these applications an oxygen (air) electrode is a promising cathode. In this study, the oxygen biocathode based on the laccase enzyme Pleurotus ostreatus HK-35 was developed and its electrochemical properties were studied depending on the immobilization method of the enzyme on the surface of a carbon-graphite electrode and the type of the electrolyte. It was experimentally established that laccase injection using a sol-gel matrix was the effective method for immobilizing laccase on the surface of a carbon-graphite electrode. It was shown that the more efficient operation of the laccase-based biocathode was observed in a phosphate-citrate (pH 4.0) buffer solution, i.e., in an acidic environment.
Electrochemical Energetics. 2024;24(1):38-49
pages 38-49 views

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