Composite solid electrolytes based on lithium doped N-methyl-N-propylpiperidinium salt

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Abstract

The effect of lithium perchlorate (LiClO4) on the transport and thermal properties of the ternary system consisting of N-methyl-N-propylpiperidinium perchlorate, highly dispersed γ-aluminum oxide (having the specific surface area of 200 m2 /g), and lithium perchlorate was investigated. It was shown that the obtained composites exhibited thermal stability up to at least 190°C. Using the impedance spectroscopy method, it was shown that the highest conductivity of solid electrolytes was ~10–5 S/cm at 40°C, x = 0.5, and 3·10–4 S/cm at x = 0.55 (T = 110°С).

About the authors

Daria A. Kyzlasova

Institute of Chemistry of a Solid body and Mechanochemistry of the Siberian Branch of RAS; Novosibirsk State University

ORCID iD: 0009-0000-7136-5339
18, Kutateladze St., Novosibirsk, 630128

Artem S. Ulihin

Institute of Chemistry of a Solid body and Mechanochemistry of the Siberian Branch of RAS

ORCID iD: 0000-0002-6795-0006
SPIN-code: 2810-7309
Scopus Author ID: 15046088200
ResearcherId: P-1187-2017
18, Kutateladze St., Novosibirsk, 630128

Nikolai F. Uvarov

Institute of Chemistry of a Solid body and Mechanochemistry of the Siberian Branch of RAS

ORCID iD: 0000-0002-8209-7533
SPIN-code: 8137-4513
18, Kutateladze St., Novosibirsk, 630128

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