Lithium borates as a surface protective layer for lithium-manganese spinel

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Abstract

The protective properties of the coating applied to the surface of lithium-manganese spinel (LiMn2O4), using the eutectic composition of Li2O : B2O3 = 47 : 53 (wt.) with the melting point of 650°C, were studied. The content of the eutectic lithium borate varied from 1% to 10%. The electrochemical behavior of the obtained materials in the cathode half-cells of lithium-ion battery was studied at room temperature. It was shown that an abnormally large decrease in the specific capacity of lithium-manganese spinel took place simultaneously with the stabilizing effect. The side chemical reactions that occur between LiMn2O4 and the eutectic lithium borate during annealing while applying a protective layer were analyzed. The chemical stability of lithium-manganese spinel (LiMn2O4) and the manganese-containing solid solution with the layered structure, LiNi1/3Mn1/3Co1/3O2, with respect to enriched lithium borates, was compared.

About the authors

Anastasia A. Koshkina

Institute of Solid State Chemistry

ORCID iD: 0000-0002-8418-9298
91 Pervomayskaya St.,

Tatiana V. Yaroslavtseva

Institute of Solid State Chemistry

ORCID iD: 0000-0003-1010-7621
91 Pervomayskaya St.,

Natalia V. Urusova

Institute of Solid State Chemistry

ORCID iD: 0000-0001-5591-4991
91 Pervomayskaya St.,

Olga G. Reznizkikh

Institute of Solid State Chemistry

ORCID iD: 0000-0002-8036-890X
91 Pervomayskaya St.,

Mikhail A. Khrustalev

Peter the Great St. Petersburg Polytechnic University

St. Petersburg, Polytechnicheskaya str., 29

Kseniya Valer'evna Nefedova

Institute of Solid State Chemistry

91 Pervomayskaya St.,

Viktor Dmitrievich Zhuravlev

Institute of Solid State Chemistry

91 Pervomayskaya St.,

Ol'ga Viktorovna Bushkova

Institute of Solid State Chemistry; NTI Competence Center of the Institute of Problems of Chemical Physics of RAS

ORCID iD: 0000-0003-2230-5705
91 Pervomayskaya St.,

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