


Vol 38, No 5 (2017)
- Year: 2017
- Articles: 13
- URL: https://ogarev-online.ru/1068-3666/issue/view/14148
Article
Influence of antifriction fillers on the surface properties of elastomers based on propylenoxide rubbers
Abstract
Novel compositions of frost-resistant rubbers (elastomers) are investigated. The possibilities of modifying the basic elastomer using several different fillers are studied. A PTFE-based filler (Forum), technical carbon (TC), and graphene oxide (GO) are tested as fillers. Mechanical, tribological, and microscopic investigations (SEM with elemental analysis and an atomic force microscope (AFM) using different modes) are performed. In order to investigate the operating parameters of these samples, the sample surface was studied before and after the friction tests. The surface topography and the distribution of individual elements over the surface are estimated. Microscopic sections of the samples are studied to obtain information concerning the bulk distribution of the chemical elements. It is shown that the use of fillers such as Forum and technical carbon leads to a better result when they are used together. Their elastic, viscous, and adhesive properties are studied using AFM (the force curve mode—“force-distance curve” and the force modulation mode—“magnitude-distance curve”). It is shown that a distinctive feature of rubber samples having the best tribological properties consists of an increase in rigidity and a decrease in adhesion in the course of tribological testing.



Improving the lubricating properties of 10W40 oil using oxidized graphite additives
Abstract
Improving the tribological properties of mineral oils is necessary for energy conservation and enhancing machine efficiency. The antifriction and antiwear properties of 10W40 oil were significantly improved by the addition of small amounts of oxidized graphite flakes. According to the X-ray photoelectron spectroscopy (XPS), this improvement was related to the oxidation of ultrasonicated graphite flakes in an ambient atmosphere accompanied by the adsorption of oxygenated compounds. The oxidation induces the defects which modify the chemical structure in an sp2 graphite lattice. The dispersion stability of graphite flakes increased in 10W40 oil due to their structural defects and adsorbed oxygen functional groups. This was found to be the main reason behind the improvement of the lubricating properties of graphite flake additives. The formation of transfer films of the graphite structure on the sliding interfaces was shown by the micro-Raman spectroscopy, which explained the improvement of the antifriction and antiwear properties of the mixture by the mechanical reasons.



Modification of graphite greases graphene nanostructures
Abstract
In the article considered the problem of the devastating impact of friction to the machine parts’ and mechanisms, and ways to solve this problem. Described the method of mechanical activation of the graphite grease in a planetary mill. Experimentally determined friction coefficients of sliding of standard and mechanically activated of the graphite grease. Established that as a result of mechanical activation friction coefficient of sliding decreases in the 2.2–2.5 times. The obtained spectra of Raman scattering allow to assume, that the reduction in the friction coefficient of sliding happens at the expense of forming in a graphite grease of graphene nanostructures.



The effect of carbon nanoadditives on the tribological properties of industrial oils
Abstract
The promising methods of production and application of carbon nanoparticles in tribology are reviewed in this work. The design and operating principles of the unit for obtaining carbon nanoparticles by the electrical arc method elaborated by us are described. The results of laboratory tests on a four-ball friction machine concerning the effect of carbon nanoadditives on the wear-resistant and antiscoring properties of industrial oil I-32A are discussed.



On the kinetics of forming an oxide film for lubrication when cutting steel in a controlled atmosphere
Abstract
An experimental study of the steel-cutting process in a controlled atmosphere is performed. Based on the results, a theoretical model is developed to evaluate the kinetics of the formation of an oxide lubricating film under steel cutting and to optimize the cutting process by decreasing the cutting forces and the wear and tear of the tool. The performed studies showed that, for the manifestation of an effective lubricating effect of pure oxygen due to the formation of a separating protective film of adsorbed oxygen, it is necessary to maintain a pressure of more than 1.32 Pa.



On the experimental techniques for assessing the specific friction force and its parameters
Abstract
The experimental techniques and conditions for assessing the specific friction force and its parameters are reviewed. The values of the specific friction force and its parameters obtained by various techniques in various ranges of the normal contact pressure are compared. The reasons behind the disagreement of the specific friction force values obtained by various techniques, as well as the conditions of their agreement, are analyzed. It is recommended that the values of the parameters of the specific friction force should be assessed under the conditions of a plastic deformation at high contact pressures not less than a half of the hardness of the softer material of the frictional pair. In the range of low contact pressures, the parameters of the specific friction force should be assessed considering the micro- and nanoroughness and the adhesive interaction between the surfaces.



Research of the mechanism and development of the wear model of a diamond tool when turning aluminum-matrix composite materials
Abstract
The results of a study of the wear mechanism of diamond tools for turning aluminum-matrix composite materials (ACMs) hardened by Al2O3, SiC, and B4C particles are presented. The study of the posterior surface topography of a diamond tool (ASPK-2) shows the presence of parallel scratches in the direction of the vector of the cutting speed; it is characteristic of abrasive wear fatigue. Research on the mass-transfer of the elements of the tool material into the chips of the treated material is carried out; it shows the presence of particles of the tool material of a size comparable to the ACM filler microparticles. The model of the abrasive-wear fatigue of a diamond tool during the turning of ACMs, considering the power of the impact of the reinforcement particles, the hardness of the tool depending on the temperature in the cutting zone, the abrasiveness, and the mass fraction of the dispersed particles reinforcing the matrix and tool geometry is proposed.



Optimal design of a frictional pair of a hub–plunger
Abstract
Based on the model of a rough friction surface, the theoretical analysis of the displacement function for the external contour points of the hub of a frictional pair, providing the absence of the initial wear and tear, which takes place towards the end of the bedding period, is carried out. The obtained displacement function for the external contour points of the hub provides increased wear resistance of the frictional pair.



Polymer thermal loading in the polytetrafluoroethylene–steel friction pair
Abstract
The comparative analysis of the calculated and experimental data concerning the polytetrafluorethylene thermal loading in friction is carried out. The conditions of achieving the quasi-stationary thermal state of a polymeric sample depending on the sliding distance are shown. The optimum value of the sliding distance taking into account the distribution coefficient of the heat flow according to Sharron’s formula is determined.



Wear resistance coatings of nickel alloys obtained by supersonic plasma torch
Abstract
The research results of coatings of nickel alloys deposited using supersonic atmospheric-plasma spraying are presented. The main feature of the work carried out is that the plasma flow is charged by powder material using the powder ring injector designed by authors. The ring powder injector unit is equipped by a gas dynamic focusing system that makes it possible to ensure the conditions of creating coatings which are not subject to wear and tear under abrasive friction.



Plastic deformation of the surface layer’s microroughness by a sliding tool with strong contact friction
Abstract
The plastic deformation of the discrete contacts of a tool with a circular-arc and an inclined profile with the periodical microroughnesses of the metallic part’s surface layer is modeled. The plane deformation theory of a perfectly plastic body is used. The plastic deformation process of the surface layer’s microroughnesses by a sliding tool with Prandtl’s high contact friction in which the plastic shear occurs in the direction of the slide of the tool, with the microroughnesses’ depressions being filled and a decrease of the surface roughness, is studied.



Analysis of changes in the mechanical properties of the surface layers of aluminum alloys under the conditions of sliding friction
Abstract
In this article the properties of surface layers of aluminum alloys before and after friction tests of different durations are studied by the indentation methods and the impact of the composition of the alloys on these properties is revealed. It is shown that as a result of wear and tear, a pliable layer is formed on the surface of one of the alloys. Conclusions about various mechanisms of the wear and tear of alloys are made based on the analysis.



Formation of adhesive bonds under contact rotaprint lubrication
Abstract
The mechanism of the formation of adhesive bonds of a friction modifier (a lubricant based on bitumen) with a wheel of railway transport is considered. Calculations performed using quantum chemical methods allow us to draw a conclusion on the existence of the physical adsorption of this lubricant on a wheel surface. The lubrication’s effectiveness can be improved using fatty acids whose introduction into the lubricating material leads to the formation of chemical bonds in the system; this is experimentally confirmed for the contact rotaprint lubrication technology.


